86369-58-6Relevant academic research and scientific papers
A Thorough Study of the Stereochemical Consequences of the Hydration/Dehydration Reaction Catalyzed by β-Hydroxydecanoyl Thioester Dehydrase
Schwab, John M.,Habib, Asif,Klassen, John B.
, p. 5304 - 5308 (1986)
β-Hydroxydecanoyl thioester dehydrase is the pivotal enzyme in the biosynthesis of unsaturated fatty acids under anaerobic conditions, catalyzing the equilibration of thioesters of (R)-3-hydroxydecanoic acid, (E)-2-decenoic acid, and (Z)-3-decenoic acid.S
Transformation of zirconocene-olefin complexes into zirconocene allyl hydride and their use as dual nucleophilic reagents: Reactions with acid chloride and 1,4-diketone
Fujita, Kazuya,Yorimitsu, Hideki,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 6776 - 6783 (2007/10/03)
Zirconocene-olefin complexes Cp2Zr(H2C=CHR), prepared in benzene-THF at 0 °C, react with acid chlorides to provide homoallylic alcohols. The key is an equilibrium between the zirconocene-olefin complexes and the corresponding zircono
