863718-09-6

Basic information

• Product Name: [(C₆H₅)PdCl(NHC₅H₁₀)(P(C₆H₅)3)]
• CAS NO: 863718-09-6
• Molecular Weight: 566.419
• Mol File: 863718-09-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₆H₅)PdCl(NHC₅H₁₀)(P(C₆H₅)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₆H₅)PdCl(NHC₅H₁₀)(P(C₆H₅)3)](863718-09-6)
• EPA Substance Registry System: [(C₆H₅)PdCl(NHC₅H₁₀)(P(C₆H₅)3)](863718-09-6)

Safety Data

• Hazardous Substances Data: 863718-09-6(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 63864-53-9 trans-[Pd(Ph)Cl(PPh₃)2] 

Relevant articles and documents

Formation of ArPdXL(amine) complexes by substitution of one phosphane ligand by an amine in trans-ArPdX(PPh3)2 complexes

Amines (piperidine, morpholine, diisopropylamine, terbutylamine), which may be used as bases in copper-free palladium-catalyzed Sonogashira reactions, substitute one phosphane PPh3 in trans-ArPdX(PPh3) 2 complexes (Ar = Ph, 4-NC-C6H4, 4-MeOC-C 6H4, 2-thienyl; X = I, Br, Cl) to generate ArPdX(PPh 3)(amine) complexes in a reversible reaction whose equilibrium constant is determined in chloroform, THF, and DMF. The equilibrium constant depends on Ar, X, the basicity, and the steric hindrance of the amine. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.