863767-22-0Relevant articles and documents
Nucleoside analogues from branched-chain pyranosides
Otero, Iran,Feist, Holger,Herrera, Lidcay,Michalik, Manfred,Quincoces, Jose,Peseke, Klaus
, p. 104 - 111 (2005)
Reaction of (pyranosid-3-yl)ethanal 2 with ethynylmagnesium bromide or lithium phenylacetylide in THF afforded (2R, S)-1-(methyl 2-O-benzyl-4,6-O- benzylidene-3-deoxy-α-D-altropyranosid-3-yl)but-3-yn-2-ols 3a and 3b, respectively. Oxidation of 3a and 3b y