86377-26-6Relevant academic research and scientific papers
Selective monocyclization of epoxy terpenoids promoted by zeolite NaY. A short biomimetic synthesis of elegansidiol and farnesiferols B-D
Tsangarakis, Constantinos,Arkoudis, Elias,Raptis, Christos,Stratakis, Manolis
, p. 583 - 586 (2008/02/02)
Epoxy terpenes cyclize readily, by confinement within zeolite NaY, to form exomethylenic cyclohexanols as the major products. The selective monocyclization of 10,11-epoxyfarnesyl acetate within NaY provides a short and efficient biomimetic route to (±)-elengasidiol and (±)-farnesiferols B-D.
Acid-catalyzed Rearrangements of Linalool Oxide
Ho, Tse-Lok,Liu, Shing-Hou
, p. 761 - 769 (2007/10/02)
Reaction of linalool oxide (1) with acids leads to a variety of dehydration products which are shown to be aliphatic dienones and /or monocyclic enones.A mechanism is proposed to account for the generation of all these compounds.
