86377-31-3Relevant academic research and scientific papers
STABLE CARBOCATIONS FROM TERPENOIDS. V. REARRANGEMENTS OF 1-SUBSTITUTED CARYOLANES IN SUPERACIDS
Gatilova, V. P.,Korchagina, D. V.,Bagryanskaya, I. Yu.,Gatilov, Yu. V.,Dubovenko, Zh. V.,et al.
, p. 5 - 19 (2007/10/02)
An experimentally substantiated scheme is proposed for the molecular rearrangements of 1-substituted caryolanes in acidic media.The behavior pattern of the intermediately formed polycyclic carbocations observed under "long-life" conditions agrees with the rearrangement paths predicted on the basis of analysis within the scope of molecular mechanics.
REACTION OF HYDROXY AND CARBONYL COMPOUNDS WITH SULFUR TETRAFLUORIDE. XIII. REACTIONS OF ALIPHATIC HYDROXY KETONES WITH SULFUR TETRAFLUORIDE
Stepanov, I. V.,Burmakov, A. I.
, p. 40 - 46 (2007/10/02)
Aliphatic α-hydroxy ketones react with sulfur tetrafluoride to form trifluoroalkanes and difluoroalkyl fluorosulfinates.The action of sulfur tetrafluoride on 4-hydroxy-2-pentanone gives 2,2,4-trifluoropentane and 3-penten-2-one.
