86377-31-3Relevant academic research and scientific papers
REACTION OF HYDROXY AND CARBONYL COMPOUNDS WITH SULFUR TETRAFLUORIDE. XIII. REACTIONS OF ALIPHATIC HYDROXY KETONES WITH SULFUR TETRAFLUORIDE
Stepanov, I. V.,Burmakov, A. I.
, p. 40 - 46 (2007/10/02)
Aliphatic α-hydroxy ketones react with sulfur tetrafluoride to form trifluoroalkanes and difluoroalkyl fluorosulfinates.The action of sulfur tetrafluoride on 4-hydroxy-2-pentanone gives 2,2,4-trifluoropentane and 3-penten-2-one.
STABLE CARBOCATIONS FROM TERPENOIDS. V. REARRANGEMENTS OF 1-SUBSTITUTED CARYOLANES IN SUPERACIDS
Gatilova, V. P.,Korchagina, D. V.,Bagryanskaya, I. Yu.,Gatilov, Yu. V.,Dubovenko, Zh. V.,et al.
, p. 5 - 19 (2007/10/02)
An experimentally substantiated scheme is proposed for the molecular rearrangements of 1-substituted caryolanes in acidic media.The behavior pattern of the intermediately formed polycyclic carbocations observed under "long-life" conditions agrees with the rearrangement paths predicted on the basis of analysis within the scope of molecular mechanics.
