863868-00-2Relevant academic research and scientific papers
Silylcuprates from allene and their reaction with α,β- unsaturatedd nitriles and imines. Synthesis of silylated oxo compounds leading to cyclopentane and cycloheptane ring formation
Barbero, Asuncion,Blanco, Yolanda,Pulido, Francisco J.
, p. 6876 - 6883 (2007/10/03)
The silylcupration of allenes and the subsequent capture of the intermediate cuprate with α,β-unsaturated nitriles is reported. The influence of the substitution of the nitrile, the nature of the silylcopper species, and the temperature on the selectivity
