863907-37-3Relevant academic research and scientific papers
Preparation and coordination chemistry of n-allylaminophosphane
Slawin, Alexandra M. Z.,Wheatley, Joanne,Woollins, J. Derek
, p. 713 - 720 (2007/10/03)
Reaction of allylamine with 1 equiv. of Ph2PCl in the presence of NEt3, proceeds in THF to give (allylamino)phosphane 1. 1 has been coordinated as a monodentate P ligand with Au, Pd, Pt, Ru, Rh, Ir and as a bidentate P,allyl ligand to Pt. Reaction of KOtBu with [PtCl2{Ph 2PNH(C3H5)}2] in methanol gives [Pt{Ph2PNH(C3H8O)}2]. The X-ray structures of 1.Se and four demonstrative monodentate complexes all reveal intramolecular N-H...Cl hydrogen bonding. The structure of [Pt{Ph 2PNH(C3H8O)}2] consists of an N-H...O hydrogen-bonded dimer in the solid state. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.
