863921-79-3

Upstream product

• 499144-88-6 (2E,5S)-5-(tert-butyldimethylsilyloxy)-6-(trityloxy)hex-2-enal 
• 188945-41-7 ethyl di-O-tolylphosphonoacetate 
• 499144-90-0 (2E,5S)-5-(tert-butyldimethylsilyloxy)-6-(trityloxy)hex-2-enol 
• 863921-74-8 ethyl (2E,5S)-5-(tert-butyldimethylsilyloxy)-6-(trityloxy)hex-2-enoate 
• 284480-80-4 (E)-(S)-5-Hydroxy-6-trityloxy-hex-2-enoic acid ethyl ester 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 124755-24-4 ethyl [bis(2,2,2-trifluoroethoxy)phosphinyl]acetate 

Downstream Products

• 863921-95-3 (2Z,4E,8E,10Z)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-12-{(4S,6R)-6-[(1E,3E)-(R)-8-(4-methoxy-benzyloxy)-nona-1,3-dienyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-dodeca-2,4,8,10-tetraenoic acid ethyl ester 

Relevant academic research and scientific papers

A convergent and stereoselective synthesis of a seco-precursor of macrolactin A

A seco-precursor of macrolactin A was synthesized by coupling two advanced segments. Wittig reaction and Horner-Emmons reaction were utilized to construct the three characteristic E,Z and E,E dienes. The C1-C10 segment was synthesize