863971-62-4

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Basic information

Product Name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Synonyms: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Milstein Catalyst Precursor;Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%
CAS NO:863971-62-4
Molecular Formula: C20H36ClN2OPRu
Molecular Weight: 489.02
EINECS: N/A
Product Categories: organometallic complex;Ru
Mol File: 863971-62-4.mol
Article Data: 0

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: pale yellow/solid
Density: N/A
Refractive Index: N/A
Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
Solubility: N/A
Sensitive: air sensitive
CAS DataBase Reference: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)(CAS DataBase Reference)
NIST Chemistry Reference: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)(863971-62-4)
EPA Substance Registry System: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)(863971-62-4)

Safety Data

Hazard Codes: Xn
Statements: 19-40
Safety Statements: 36/37
WGK Germany: 3
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 863971-62-4(Hazardous Substances Data)

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Cas No: 863971-62-4
USD $ 139.0-210.0 / Kilogram
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Zhuozhou Wenxi import and Export Co., Ltd
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Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)
Cas No: 863971-62-4
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Suzhou Health Chemicals Co., Ltd.
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5-BroMo[1,2,4]triazolo[1,5-a]pyridine
Cas No: 863971-62-4
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Henan Allgreen Chemical Co.,Ltd
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N- diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Cas No: 863971-62-4
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BOC Sciences
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Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II), Min. 98% (Milstein Catalyst Precursor)
Cas No: 863971-62-4
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Antimex Chemical Limied
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Cas No: 863971-62-4
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ZHEJIANG JIUZHOU CHEM CO.,LTD
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)
Cas No: 863971-62-4
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10 Milligram
Amadis Chemical Co., Ltd.
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)863971-62-4
Cas No: 863971-62-4
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Shanghai Hanhong Scientific Co.,Ltd.
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Carbonylchlorohydrido[6-(di-t-butylphosphino methyl)-2-(N,N-diethylaminomethyl)pyridine] ruthenium(II),
Cas No: 863971-62-4
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Cerametek Materials（ShenZhen）Co., Ltd.
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Cas No: 863971-62-4
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Strem Chemicals, Inc.
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863971-62-4 Usage

Reaction

Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone

Uses

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

General Description

May contain up to 10% acetone and/or THF.

Check Digit Verification of cas no

The CAS Registry Mumber 863971-62-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,3,9,7 and 1 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 863971-62:
(8*8)+(7*6)+(6*3)+(5*9)+(4*7)+(3*1)+(2*6)+(1*2)=214
214 % 10 = 4
So 863971-62-4 is a valid CAS Registry Number.

863971-62-4 Well-known Company Product Price

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(Code)Product description
CAS number
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Detail

Aldrich
(735809) [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
863971-62-4
735809-100MG
1,287.00CNY
Detail

Aldrich
(735809) [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
863971-62-4
735809-500MG
4,636.71CNY
Detail

863971-62-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name	carbon monoxide,chlororuthenium,N-[[6-(ditert-butylphosphanylmethyl)pyridin-2-yl]methyl]-N-ethylethanamine

1.2 Other means of identification

Product number	-
Other names	Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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