864064-14-2Relevant academic research and scientific papers
Novel method for the preparation of enantiomerically pure propargylic substituted compounds
Nishibayashi, Yoshiaki,Imajima, Hiroaki,Onodera, Gen,Uemura, Sakae
, p. 4106 - 4109 (2005)
We have found a novel method for the preparation of enantiomerically pure propargylic alkylated compounds from an achiral propargylic alcohol assisted by a ruthenium complex bearing BINAP as a chiral ligand. It is noteworthy that products bearing completely opposite configurations are obtained with an almost 100% ee.
