86409-98-5Relevant academic research and scientific papers
Substitution Reactions of Carbon Nucleophiles with β-(Phenylseleno)vinyl Sulfone Se Oxides
Back, Thomas G.,Krishna, M. Vijaya
, p. 4265 - 4269 (2007/10/02)
Selenoxides 2, obtained from the selenosulfonation and peracid oxidation of acetylenes, reacted with various nucleophiles to afford the products of overall substitution of the PhSeO moiety.Anions of dimethyl malonate, ethyl acetoacetate, malononitrile, 1-
Reactions of amines with β-(phenylseleninyl)vinyl sulfones derived from the selenosulfonation of acetylenes. Formation of enamine sulfones
Back, Thomas G.,Collins, Scott,Law, Kwok-Wai
, p. 2313 - 2318 (2007/10/02)
β-(Phenylseleno)vinyl sulfones 2 were prepared from the selenosulfonation of acetylenes and were oxidized to the corresponding selenoxides 3.These were treated in situ with morpholine (4) or pyrrolidine (5) to afford the corresponding enamine sulfones 6 a
