86428-01-5

Basic information

• Product Name: tropone azine
• Synonyms: tropone azine
• CAS NO: 86428-01-5
• Molecular Weight: 208.263
• Mol File: 86428-01-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tropone azine(CAS DataBase Reference)
• NIST Chemistry Reference: tropone azine(86428-01-5)
• EPA Substance Registry System: tropone azine(86428-01-5)

Safety Data

• Hazardous Substances Data: 86428-01-5(Hazardous Substances Data)

Upstream product

• 62515-92-8 N-p-methoxyphenyl-2,4,6-cycloheptatriene-1-imine 

Downstream Products

• 79-36-7 dichloroacethyl chloride 
• 613-31-0 9,10-dihydroanthracene 
• 120-12-7 anthracene 

Relevant articles and documents

FORMATIONS OF 1,1'-BIAZAAZULANONES THROUGH, -TYPE CYCLOADDITION REACTIONS OF TROPONE AZINE WITH HETEROCUMULENES

Reaction of N-aryl-2,4,6-cycloheptatrien-1-imine with hydrazine afforded tropone azine, which reacted with chloroketenes to give 1,1'-biazaazulanones via -type cycloadducts followed by elimination of hydrochloride.The similar reaction using phenyl isocyanate afforded a -type 1:2 cycloadduct, while the reaction with phenyl isocyanate yielded only a 1:1 cycloadduct. 15N and 13C nmr spectra on C=N bond of tropone azine showed a minor contribution of a dipolar structure compared with the case of N-aryl-2,4,6-cycloheptatrien-1-imines.