864358-25-8

Basic information

• Product Name: Ir(2-pyridylphenyl)2(2-(2-pyridyl)phosphaethene)OTf
• CAS NO: 864358-25-8
• Molecular Weight: 1017.19
• Mol File: 864358-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir(2-pyridylphenyl)2(2-(2-pyridyl)phosphaethene)OTf(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(2-pyridylphenyl)2(2-(2-pyridyl)phosphaethene)OTf(864358-25-8)
• EPA Substance Registry System: Ir(2-pyridylphenyl)2(2-(2-pyridyl)phosphaethene)OTf(864358-25-8)

Safety Data

• Hazardous Substances Data: 864358-25-8(Hazardous Substances Data)

Upstream product

• 153297-46-2 bis(2-phenylpyridine-C²,N)-bis(aquo)iridium(III) trifluoromethanesulfonate 
• 144404-03-5 2-(2-pyridyl)phosphaethene 

Relevant articles and documents

Cationic iridium(III) complexes bearing phosphaalkene and 2-pyridylphenyl ligands

The reactions of [Ir(ppy)2(H2O)2](OTf) (ppy = 2-pyridylphenyl) with 1,2-diaryl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]cyclobutenes (DPCB-Y) afford [Ir(ppy)2(DPCB-Y)](OTf) (Y = CF3 (1), H (2), and OMe (3)) in high yields. The 2-(2-pyridyl)phosphaethene (PN) analogue [Ir(ppy)2(PN)](OTf) (4) is prepared in a similar manner. Complexes 1-4 are characterized by elemental analysis, NMR and electronic spectroscopy, cyclic voltammetry, and/or X-ray structural analysis.