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864377-31-1

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864377-31-1 Usage

Uses

2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine is a useful research chemical.

Chemical Properties

white powder

Check Digit Verification of cas no

The CAS Registry Mumber 864377-31-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,4,3,7 and 7 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 864377-31:
(8*8)+(7*6)+(6*4)+(5*3)+(4*7)+(3*7)+(2*3)+(1*1)=201
201 % 10 = 1
So 864377-31-1 is a valid CAS Registry Number.

864377-31-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(3-Bromophenyl)-4,6-diphenyl-1,3,5-triazine

1.2 Other means of identification

Product number -
Other names 1,3,5-Triazine,2-(3-bromophenyl)-4,6-diphenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:864377-31-1 SDS

864377-31-1Synthetic route

2-chloro-4,6-diphenyl-1,3,5-triazine
3842-55-5

2-chloro-4,6-diphenyl-1,3,5-triazine

(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
(3-Bromophenyl)methanol
15852-73-0

(3-Bromophenyl)methanol

benzamidin
618-39-3

benzamidin

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With oxygen In toluene at 110℃; for 20h; Schlenk technique;90%
benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

3-bromobenzyl chloride
932-77-4

3-bromobenzyl chloride

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With sodium carbonate; sulfur In dimethyl sulfoxide at 130℃; for 24h;90%
With sulfur; potassium hydroxide In dimethyl sulfoxide at 130℃; for 24h; Sealed tube;88%
2-bromo-4,6-diphenyl-1,3,5-triazabenzene
80984-79-8

2-bromo-4,6-diphenyl-1,3,5-triazabenzene

(3-bromophenyl)boronic acid
89598-96-9

(3-bromophenyl)boronic acid

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 5h; Inert atmosphere;87.46%
Suzuki Coupling;
Suzuki Coupling;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

((4,6-diphenyl-1,3,5-triazin-2-yl)boronic acid)

((4,6-diphenyl-1,3,5-triazin-2-yl)boronic acid)

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 5h; Inert atmosphere;83.1%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2,4-diphenyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1,3,5-triazine

2,4-diphenyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1,3,5-triazine

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 10h; Suzuki Coupling; Inert atmosphere; Reflux;83%
m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With nickel diacetate; sodium carbonate In toluene at 110℃; for 30h; Reagent/catalyst;83%
With copper(II) acetate monohydrate; sodium carbonate In toluene at 100℃; for 24h;68%
With sodium carbonate; copper(l) chloride at 90 - 100℃;3.2 g
N-(3-bromobenzylidene)-phenyl-amine
18467-14-6

N-(3-bromobenzylidene)-phenyl-amine

benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 12h; Reflux;74%
Stage #1: N-(3-bromobenzylidene)-phenyl-amine; benzamidine monohydrochloride With sodium hydroxide In ethanol at 80℃; for 16h; Inert atmosphere;
Stage #2: With sodium t-butanolate In ethanol at 80℃; for 16h; Inert atmosphere;
37%
Stage #1: N-(3-bromobenzylidene)-phenyl-amine; benzamidine monohydrochloride With sodium hydroxide In ethanol at 80℃; for 16h; Inert atmosphere;
Stage #2: With sodium t-butanolate In ethanol at 80℃; for 16h;
37%
Stage #1: N-(3-bromobenzylidene)-phenyl-amine; benzamidine monohydrochloride With sodium hydroxide In ethanol for 18h; Inert atmosphere; Reflux;
Stage #2: With sodium t-butanolate In ethanol for 16h; Inert atmosphere; Reflux;
26.7%
3-bromobenzoyl chloride
1711-09-7

3-bromobenzoyl chloride

benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: 3-bromobenzoyl chloride; benzamidine monohydrochloride With triethylamine In 5,5-dimethyl-1,3-cyclohexadiene at 0 - 60℃; for 3.5h; Inert atmosphere;
Stage #2: With 1,1,3,3-tetramethyldisilazane In 5,5-dimethyl-1,3-cyclohexadiene at 150℃; for 5h; Inert atmosphere;
72%
2-chloro-4,6-diphenyl-1,3,5-triazine
3842-55-5

2-chloro-4,6-diphenyl-1,3,5-triazine

(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)bromobenzene)
594823-67-3

(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)bromobenzene)

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane for 5h; Inert atmosphere; Reflux;72%
3-bromobenzoyl chloride
1711-09-7

3-bromobenzoyl chloride

benzonitrile
100-47-0

benzonitrile

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: 3-bromobenzoyl chloride; benzonitrile In dichloromethane at 0 - 5℃; for 0.5h; Inert atmosphere; Cooling with ice;
Stage #2: With antimonypentachloride In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #3: With ammonia In water at 0 - 20℃; for 3.5h; Cooling with ice;
66.7%
Stage #1: 3-bromobenzoyl chloride; benzonitrile With aluminum (III) chloride; thionyl chloride In 1,2-dichloro-benzene at 100℃; for 20h;
Stage #2: With ammonium chloride In 1,2-dichloro-benzene at 100℃; for 3h;
40%
m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

benzimidamide hydrochloride

benzimidamide hydrochloride

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With sodium carbonate; copper dichloride In toluene at 130℃;52%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2-chloro-4,6-diphenyl-1,3,5-triazine
3842-55-5

2-chloro-4,6-diphenyl-1,3,5-triazine

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran-d8 at -78℃; for 1h;
Stage #2: 2-chloro-4,6-diphenyl-1,3,5-triazine In tetrahydrofuran at 20℃; for 5h;
40.4%
With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 12h;28%
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: 2-chloro-4,6-diphenyl-1,3,5-triazine In tetrahydrofuran; hexane at 20℃; for 3h;
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

2-chloro-4,6-diphenyl-1,3,5-triazine
3842-55-5

2-chloro-4,6-diphenyl-1,3,5-triazine

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: 1-Bromo-3-iodobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere;
Stage #2: 2-chloro-4,6-diphenyl-1,3,5-triazine In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;
30%
With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Inert atmosphere;30%
Stage #1: 1-Bromo-3-iodobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere;
Stage #2: 2-chloro-4,6-diphenyl-1,3,5-triazine In tetrahydrofuran at -78 - 20℃; for 1.5h; Inert atmosphere;
30%
m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: toluene / 8 h / Reflux
2.1: sodium hydroxide / ethanol / 16 h / 80 °C / Inert atmosphere
2.2: 16 h / 80 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: ethanol / 3 h / 20 °C
2: sodium hydroxide / ethanol / 12 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1.1: toluene / 8 h / Reflux
2.1: sodium hydroxide / ethanol / 16 h / 80 °C / Inert atmosphere
2.2: 16 h / 80 °C
View Scheme
Multi-step reaction with 2 steps
1.1: toluene / 8 h / Inert atmosphere; Reflux; Dean-Stark
2.1: sodium hydroxide / ethanol / 18 h / Inert atmosphere; Reflux
2.2: 16 h / Inert atmosphere; Reflux
View Scheme
2-chloro-4,6-diphenyl-1,3,5-triazine
3842-55-5

2-chloro-4,6-diphenyl-1,3,5-triazine

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; tricyclohexylphosphine / N,N-dimethyl-formamide / 12 h / Inert atmosphere; Reflux
2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 10 h / Inert atmosphere; Reflux
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / 1,4-dioxane; toluene; water / 6 h / 100 °C
2: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / 1,4-dioxane; toluene / 12 h / 100 °C
View Scheme
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-tetramethyl-2-(5'-phenyl-[1,1’:3' ,1

4,4,5,5-tetramethyl-2-(5'-phenyl-[1,1’:3' ,1"-terphenyl]-4-yl)-1,3,2-dioxaborolane

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane for 17h; Reflux;96%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 90℃; for 12h; Reflux;96.8%
With bis-triphenylphosphine-palladium(II) chloride; potassium acetate In tetrahydrofuran at 80℃; for 3h; Inert atmosphere;93%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

3-(2-pyridyl)-9H-carbazole

3-(2-pyridyl)-9H-carbazole

3-(3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole

3-(3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water for 17h; Inert atmosphere; Reflux;96%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-(2,8-diphenyldibenzo[b,d]thiophen-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(2,8-diphenyldibenzo[b,d]thiophen-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

C45H29N3S

C45H29N3S

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In 1,2-dimethoxyethane; water; toluene for 16h; Inert atmosphere; Reflux;95%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

2-(3'-chloro-[1,1'-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine

2-(3'-chloro-[1,1'-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;95%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C24H15N

C24H15N

C45H28N4

C45H28N4

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 110℃; for 15h; Inert atmosphere;95%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C24H13NO

C24H13NO

C45H26N4O

C45H26N4O

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 3h; Reflux;95%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C28H18Br2Cl2SiZn2

C28H18Br2Cl2SiZn2

C70H46Br2N6Si

C70H46Br2N6Si

Conditions
ConditionsYield
In toluene for 12h; Inert atmosphere; Reflux;94%
((3-(dibenzo[b,d]thiophen-4-yl)phenyl)boronic acid)
1307859-67-1

((3-(dibenzo[b,d]thiophen-4-yl)phenyl)boronic acid)

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-(3'-(dibenzo[b,d]thiophen-4-yl)-[1,1'-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine

2-(3'-(dibenzo[b,d]thiophen-4-yl)-[1,1'-biphenyl]-3-yl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran; water for 1h; Suzuki-Miyaura Coupling; Reflux; Inert atmosphere;93%
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran; water at 80℃; for 15h; Inert atmosphere;81.5%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-phenyl-4H-thieno[3,2-b]indole

2-phenyl-4H-thieno[3,2-b]indole

C37H24N4S

C37H24N4S

Conditions
ConditionsYield
With tri-tert-butyl phosphine; sodium t-butanolate In toluene for 12h; Reflux; Inert atmosphere;92%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,10-phenanthroline

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,10-phenanthroline

4,6-diphenyl-2-[3-(1,10-phenanthrolin-2-yl)phenyl]-1,3,5-triazine

4,6-diphenyl-2-[3-(1,10-phenanthrolin-2-yl)phenyl]-1,3,5-triazine

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; triphenylphosphine In tetrahydrofuran for 19h; Inert atmosphere; Reflux;91%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C27H19NO

C27H19NO

C48H32N4O

C48H32N4O

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene at 145℃; for 3h; Inert atmosphere;90%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

7H-spiro[chromeno[2,3-b]carbazole-13,9'-fluorene]

7H-spiro[chromeno[2,3-b]carbazole-13,9'-fluorene]

C52H32N4O

C52H32N4O

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 4h; Inert atmosphere; Reflux;90%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

anthracene-9-boronic acid
100622-34-2

anthracene-9-boronic acid

2-(3-(anthracen-9-yl)phenyl)-4,6-diphenyl-1,3,5-triazine

2-(3-(anthracen-9-yl)phenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In ethanol; water; toluene for 22h; Inert atmosphere; Reflux;90%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In ethanol; water; toluene for 18h; Inert atmosphere; Reflux;90%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

(5-phenyl-5H-benzofuro[3,2-c]carbazol-11-yl)boronic acid

(5-phenyl-5H-benzofuro[3,2-c]carbazol-11-yl)boronic acid

C45H28N4O

C45H28N4O

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Reflux; Inert atmosphere;90%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-(5-(dibenzo[b,d]thiophen-4-yl)-[1,1'-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(5-(dibenzo[b,d]thiophen-4-yl)-[1,1'-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

C45H29N3S

C45H29N3S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane; water for 14h; Inert atmosphere; Reflux;89%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C22H13NO2

C22H13NO2

C43H26N4O2

C43H26N4O2

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 5h; Inert atmosphere; Reflux;89%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C12H7N3S

C12H7N3S

C33H20N6S

C33H20N6S

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 5h; Inert atmosphere; Reflux;89%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C22H15N

C22H15N

C43H28N4

C43H28N4

Conditions
ConditionsYield
Stage #1: 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine; C22H15N With sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 0.5h; Heating;
Stage #2: With bis(tri-t-butylphosphine)palladium(0) In 1-methyl-pyrrolidin-2-one; 5,5-dimethyl-1,3-cyclohexadiene for 2h; Buchwald-Hartwig Coupling; Reflux;
88.4%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

3-[4-(2-pyridyl)phenyl]carbazole

3-[4-(2-pyridyl)phenyl]carbazole

3-[4-(2-pyridyl)phenyl]-9-[3-(4,6-diphenyltriazin-2-yl)phenyl]carbazole

3-[4-(2-pyridyl)phenyl]-9-[3-(4,6-diphenyltriazin-2-yl)phenyl]carbazole

Conditions
ConditionsYield
With 18-crown-6 ether; tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene; toluene for 4h; Inert atmosphere; Reflux;88%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C26H17BO2

C26H17BO2

C47H29N3

C47H29N3

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;88%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

B-[6-(9-phenyl-9H-carbazol-3-yl)-4-dibenzofuranyl]boronic acid

B-[6-(9-phenyl-9H-carbazol-3-yl)-4-dibenzofuranyl]boronic acid

3-{6-[3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]dibenzofuran-4-yl}-9-phenyl-9H-carbazole

3-{6-[3-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl]dibenzofuran-4-yl}-9-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water for 16h; Suzuki Coupling; Reflux;87%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

4,4,5,5-tetramethyl-2-(7-phenyldibenzo[b,e][1,4]dioxin-2-yl)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-(7-phenyldibenzo[b,e][1,4]dioxin-2-yl)-1,3,2-dioxaborolane

2,4-diphenyl-6-(3-(7-phenyldibenzo[b,e][1,4]dioxin-2-yl)phenyl)-1,3,5-triazine

2,4-diphenyl-6-(3-(7-phenyldibenzo[b,e][1,4]dioxin-2-yl)phenyl)-1,3,5-triazine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene for 8h; Heating;87%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C30H17NS

C30H17NS

C51H30N4S

C51H30N4S

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene for 11h; Inert atmosphere; Reflux;87%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C36H25BN2O2

C36H25BN2O2

C57H37N5

C57H37N5

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 95℃; for 6h; Inert atmosphere;87%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

2-(3-iodophenyl)-4,6-diphenyl-1,3,5-triazine

2-(3-iodophenyl)-4,6-diphenyl-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: 2-(3-bromophenyl)-4,6-diphenyl-[1,3,5]triazine With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: With iodine In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere;
87%
2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine
864377-31-1

2-(3-bromo-phenyl)-4,6-diphenyl-1,3,5-triazine

C23H14BNO3

C23H14BNO3

C44H26N4O

C44H26N4O

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 110℃; for 5h; Inert atmosphere;86.49%

864377-31-1Relevant articles and documents

Electron transport material, preparation method thereof and organic light-emitting device

-

Paragraph 0067-0071; 0080-0084, (2021/04/14)

The invention discloses an electron transport material, a preparation method thereof and an organic light-emitting device, and belongs to the technical field of chemical and organic light-emitting materials, in the structural general formula of the electron transport material, m and n are independently 0 or 1, and m and n are not 0 at the same time; W, Q and Z are independently C or N, and at least one of W, Q and Z is N; X and Y are independently O or S. By introducing a benzoheterocycle rigid structure, the electron transport material provided by the invention has good film-forming property and thermal stability. The electron transport material provided by the invention has high electron injection and movement rates. The electron transport material can improve the electron transport efficiency from an electron transport layer to a light-emitting layer, thereby improving the light-emitting efficiency of a device, reducing the driving voltage of the device, and enhancing the durability of the obtained organic light-emitting device.

Heterocyclic com pounds and organic light-emitting diode including the same

-

, (2021/01/19)

The present invention relates to a novel heterocyclic compound and an organic electroluminescent device comprising the same. The heterocyclic compound is represented by the following Chemical Formula 1, and the organic electroluminescent device including the heterocyclic compound has excellent driving voltage, luminous efficiency, and lifespan properties. Chemical Formula 1. (by machine translation)

Electron transporting and hole blocking organic material and application thereof in thin-film light-emitting diode

-

Paragraph 0005, (2020/11/02)

The invention provides an electron transporting and hole blocking material with an A-D-A link structure as a core. The material is applied to a thin-film semiconductor light-emitting diode, for example, an organic light-emitting diode and a quantum dot thin-film light-emitting diode; and the molecule of the material takes bipolar carbazole and a derivative group thereof as electron donating centers, so a relatively high triplet state energy level can be maintained to ensure exciton blocking capability.

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