864415-96-3Relevant academic research and scientific papers
Synthesis, electrochemistry and spectral studies on cobalt(II) and manganese (II) complexes with 12-,14-,15-, and 18-membered N4, N 2O2, N2O2S, N6 donor macrocyclic ligands
Chandra, Sulekh,Kumar, Rajiv
, p. 161 - 170 (2005)
13-, 14-, 15-, and 18-membered N2O2, N4, N2O2S, and N6 donor macrocyclic ligands and their complexes with cobalt(II) and manganese(II) of the general composition ML,(NCS)2 (where M = cobalt(II) and manganese(II) and ligands L = L1, L2, L3, and L4 have been synthesized. All of the macrocyclic ligands and their complexes have been characterized by elemental analyses, IR, mass, 1H NMR, magnetic moments, electronic and EPR spectral studies. The structures of the complexes and the various coordinating groups such as >C=N, >CONH, Ph-O-CH 2- and >NH are discussed. The redox properties of the complexes were examined by cyclic voltammetery. They exhibit a high potential Co(III)/Co(II) couple along with ligand reduction. Copyright
