864444-96-2

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 51246-20-9 1-phenyl-1-iodoethylene 
• 864444-88-2 (R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[(3aR,4R,6S,7S,7aR)-7-(tert-butyl-dimethyl-silanyloxy)-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl]-1-phenyl-ethanol 
• 864444-90-6 (R)-1-[(3aR,4R,6S,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl]-1-phenyl-ethane-1,2-diol 
• 864444-92-8 (S)-[(3aR,4R,6S,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl]-hydroxy-phenyl-acetaldehyde 
• 864444-85-9 (R)-1-((3aR,4R,6S,7S,7aS)-7-Hydroxy-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-1-phenyl-ethane-1,2-diol 
• 864444-83-7 (R)-1-Phenyl-1-((3aR,4R,7aS)-2,2,4-trimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)-ethane-1,2-diol 
• 864444-82-6 2,2,4-trimethyl-6-(1-phenyl-vinyl)-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran 
• 864444-93-9 (S)-[(3aR,4R,6S,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl]-hydroxy-phenyl-acetic acid methyl ester 

Downstream Products

• 864445-03-4 (3S,3aS,5R,6R,7R,7aS)-3,6-Dihydroxy-7-methoxy-5-methyl-3-phenyl-hexahydro-furo[3,2-b]pyran-2-one 
• 623148-34-5 (2S)-methyl 3,7-anhydro-2-phenyl-5-O-methyl-8-deoxy-α-D-altro-octitolate 
• 864444-97-3 (3S,3aS,5R,6S,7R,7aS)-3,6,7-Trihydroxy-5-methyl-3-phenyl-hexahydro-furo[3,2-b]pyran-2-one 

Relevant academic research and scientific papers

Synthesis of the branched C-glycoside substructure of altromycin B

(Chemical Equation Presented) Tungsten-catalyzed cycloisomerization of alkynyl alcohols including 8 provides only the endocyclic enol ether (11) as a key intermediate for the branched Oglycoside substructure (2) of altromycin B. A sequence of Stille cross