86445-53-6Relevant articles and documents
PREPARATION AND REACTIONS OF 1-CYANOMETHYL-2,4,6-TRISUBSTTUTED PYRIDINIUM YLIDS
Katritzky, Alan R.,Yeung, Wing Kai,Patel, Ranjan C.,Burgess, Kevin
, p. 623 - 632 (2007/10/02)
Aminoacetonitrile with pyrylium forms pyridiniums which are acylated to solvatochromic ylids.Pyrolysis of ylid (10a) (R=p-toluoyl) gives 3-cyano-2,4,6-triphenylpyridine. 1-Cyanomethyl-pyridinium (6) gives tetrahydroindolizines with α,β-unsaturated carbonyl compounds.