86447-31-6

Basic information

• Product Name: 2-Pentanamine, 1-bromo-4-methyl-, hydrobromide, (S)-
• Synonyms: 2-Pentanamine, 1-bromo-4-methyl-, hydrobromide, (S)-
• CAS NO: 86447-31-6
• Molecular Formula: C6H15Br2N
• Molecular Weight: 260.998
• Mol File: 86447-31-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 228.4°C at 760 mmHg
• Flash Point: 91.9°C
• Appearance: /
• Vapor Pressure: 0.053mmHg at 25°C
• CAS DataBase Reference: 2-Pentanamine, 1-bromo-4-methyl-, hydrobromide, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentanamine, 1-bromo-4-methyl-, hydrobromide, (S)-(86447-31-6)
• EPA Substance Registry System: 2-Pentanamine, 1-bromo-4-methyl-, hydrobromide, (S)-(86447-31-6)

Safety Data

• Hazardous Substances Data: 86447-31-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H14BrN.BrH/c1-5(2)3-6(8)4-7;/h5-6H,3-4,8H2,1-2H3;1H/t6-;/m0./s1

Upstream product

• 23032-21-5 D-leucine methyl ester 
• 2666-93-5 (S)-Leu-OMe 
• 16369-17-8 2-amino-4-methylpentan-1-ol 
• 7533-40-6 2-amino-4-methyl-1-pentanol 
• 61-90-5 L-leucine 
• 7533-40-6 (S)-2-amino-4-methylpentan-1-ol 

Downstream Products

• 88264-65-7 (S)-2-amino-4-methyl-1-pentanethiol 

Relevant articles and documents

Synthesis of amidoalkyl imidazol-2-ylidene ligands and their application to enantioselective copper-catalysed conjugate addition

A small library of precursors to chiral amidoalkyl imidazol-2-ylidene ligand was synthesised via a two-step procedure starting from commercially available amino alcohols. Preliminary screening of these bidentate ligands for the enantioselective copper-catalysed conjugate addition of diethyl zinc to cyclohexenone revealed some moderate ee values. Related chiral iminoalkyl imidazole-2-ylidene ligands demonstrated much poorer enantioselectivity. The results indicate that chelation involving a covalent copper-nitrogen bond gives better selectivity than that arising from a dative copper-nitrogen co-ordination. Georg Thieme Verlag Stuttgart.

Synthesis and properties of novel chiral-amine-functionalized ionic liquids

A novel class of chiral-amine-functionalized ionic liquids (CAFILs) has been synthesized efficiently from natural amino acids, and their structures have been determined by spectroscopic analysis and low temperature X-ray diffraction analysis. The CAFILs have been characterized by physical properties such as melting point, glass transition temperature, thermal degradation and specific rotation. NMR measurements indicate that the CAFILs may be promising alternatives in the field of chiral discrimination.

Stereochemistry and Reactions of Aziridinylphosphinothionates Derived from Amino Acids

Aziridinylphosphinothionates were prepared from optically active ethyl hydrogen phenylphosphonothionates and 1-bromo-2-alkanamines derived from leucine or valine.The aziridine ring was opened by the action of some nucleophiles.Refluxing the aziridinylphosphinethionates in acetone with sodium iodide caused hydrolysis accompanied by the rearrangement of the sulfur atom to give β-mercaptoethylphosphonamidates.The reaction mechanism was discussed eith stereochemical considerations.The insecticidal activity of the products was also examined.