864680-19-3Relevant academic research and scientific papers
Synthesis and reactivity of novel alkali metal stannides
Schollmeier, Thorsten,Englich, Ulrich,Fischer, Roland,Prass, Ingo,Ruhlandt, Karin,Schürmann, Markus,Uhlig, Frank
, p. 1462 - 1470 (2004)
Reactivity and side products of reactions of diorganodihydridostannanes (R2SnH2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR′2Si)R″2SnK (R, R′= Me, Ph; R″= , Me, tBu, Ph) 4-9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR′ 2Si)2SnR″2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSntBu3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.
