864712-80-1

Basic information

• Product Name: (E)-3-{(2R,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxiranyl}-acrylic acid methyl ester
• Synonyms: (E)-3-{(2R,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxiranyl}-acrylic acid methyl ester
• CAS NO: 864712-80-1
• Molecular Weight: 937.417
• Mol File: 864712-80-1.mol

Chemical Properties

• CAS DataBase Reference: (E)-3-{(2R,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxiranyl}-acrylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-{(2R,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxiranyl}-acrylic acid methyl ester(864712-80-1)
• EPA Substance Registry System: (E)-3-{(2R,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxiranyl}-acrylic acid methyl ester(864712-80-1)

Safety Data

• Hazardous Substances Data: 864712-80-1(Hazardous Substances Data)

Upstream product

• 864712-71-0 Methanesulfonic acid (1S,2R,3R,4R)-2,3-bis-benzyloxy-10-(tert-butyl-diphenyl-silanyloxy)-4-methyl-1-((R)-2-oxo-[1,3]dioxolan-4-yl)-4-triethylsilanyloxy-decyl ester 
• 864712-72-1 {(2R,3R)-3-[(1S,2R,3R)-1,2-Bis-benzyloxy-9-(tert-butyl-diphenyl-silanyloxy)-3-methyl-3-triethylsilanyloxy-nonyl]-oxiranyl}-methanol 
• 81255-14-3 methyl 2,3-di-O-benzyl-4-C-methyl-α-D-glucopyranoside 
• 887769-11-1 C₅₃H₈₂O₅Si₃ 
• 887768-99-2 4,5-bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodec-2-en-1-ol 
• 887768-96-9 methyl 2,3-di-O-benzyl-6-iodo-4-C-methyl-α-D-glucopyranoside 
• 864712-74-3 (E,4S,5R,6S,7R,8R)-methyl 6,7-bis(benzyloxy)-14-t-butyldiphenylsiloxy-8-triethylsiloxy-5-(4-methoxybenzyloxy)-2,4,8-trimethyltetradec-2-enoate 
• 864712-79-8 {(2R,3R)-3-[(2R,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-3-(4-methoxybenzyloxy)-6-methyldodecan-2-yl]-2-methyloxiran-2-yl}methanol 
• 864712-78-7 (2S,3R)-3-[(1R,2R,3S,4R,5R)-3,4-Bis-benzyloxy-11-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-1,5-dimethyl-5-triethylsilanyloxy-undecyl]-2-methyl-oxirane-2-carbaldehyde 
• 864712-77-6 (2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-3-(4-methoxybenzyloxy)-2,6-dimethyldodeca-1-ol 
• 887769-16-6 (2R,3R,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,6-dimethyl-6-triethylsilanyloxy-dodecanal 
• 864712-70-9 (2S,3S,4S,5R,6R)-methyl 4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-2,3-dihydroxy-6-methyldodecanoate 
• 887769-01-9 (R)-4-[(1S,2S,3R,4R)-2,3-bis(benzyloxy)-10-t-butyldiphenylsiloxy-4-triethylsiloxy-1-hydroxy-4-methyldecyl]-1,3-dioxolan-2-one 
• 864712-66-3 (2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-2,6-dimethyldodecane-1,3-diol 

Downstream Products

• 864712-65-2 (2R,3R,4S,5R,6R)-2-{(2R,3R)-3-[(E)-2-(methoxycarbonyl)vinyl]-3-methyloxiran-2-yl}-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-6-methyldodecan-3-yl dimethylcarbamate 

Relevant articles and documents

Asymmetric synthesis of the polyol subunit of the macrolide antibiotic, ossamycin: A unique approach utilizing stereochemical specificity

An asymmetric synthesis of the C1-C16 polyol subunit 2 of the macrolide antibiotic ossamycin (1) has been achieved through stepwise carbon-chain elongation reaction from D-glucose, based on a chiral pool approach. An outstanding point of this strategy is

Asymmetric synthesis of the polyol subunit of the macrolide antibiotic, ossamycin

An asymmetric synthesis of the C1-C16 polyol subunit of the macrolide antibiotic, ossamycin, has been achieved through stepwise carbon-chain elongation reaction from D-glucose.