86476-99-5Relevant academic research and scientific papers
Synthesis of sulfides by reactions of 1,1-dichloro-2-chloro- methylcyclopropane with S-nucleophiles
Mikhed'kina,Nedel'ko,Prezhdo
, p. 370 - 375 (2005)
1,1-Dichloro-2-chloromethylcyclopropane reacts with thiolates to give 2,2-dichlorocyclopropylmethyl sulfides via replacement of the side-chain chlorine atom. The resulting sulfides are readily oxidized to the corresponding sulfones.
Two way reactivity of 1,1-dichloro-2-(chloromethyl)cyclopropane in basic medium: A simple synthesis of 1,1-bis(aryloxy)-2-methylenecyclopropanes
Jonczyk,Kmiotek-Skarzynska
, p. 985 - 989 (2007/10/02)
1,1-Dichloro-2-(chloromethyl)cyclopropane (1) reacts with phenols 2a-1, alcohols 2m,n or thiophenol (2o) in different base/solvent systems, to form either 2-(aryloxymethyl)-1,1-dichlorocyclopropanes 3 and/or 1,1-bis(aryloxy)-2-methylenecyclopropanes 4. Re
A NEW REACTION OF 1,1-DICHLORO-2-HALOMETHYLCYCLOPROPANES IN BASIC MEDIUM
Jonczyk, Andrzej,Dabrowski, Miroslaw,Wozniak, Witold
, p. 1065 - 1066 (2007/10/02)
Utilization of nucleophilic reagents with 1b allows for the simple preparation of methylenecyclopropane derivatives 3 via elimination-addition routes.
