864862-22-6

Basic information

• Product Name: Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-5-azido-3,4-dihydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester
• Synonyms: Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-5-azido-3,4-dihydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester
• CAS NO: 864862-22-6
• Molecular Weight: 451.524
• Mol File: 864862-22-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-5-azido-3,4-dihydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-5-azido-3,4-dihydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester(864862-22-6)
• EPA Substance Registry System: Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-5-azido-3,4-dihydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester(864862-22-6)

Safety Data

• Hazardous Substances Data: 864862-22-6(Hazardous Substances Data)

Upstream product

• 371123-22-7 phenyl 2-amino-2-deoxy-1-thio-β-D-glucopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 
• 166516-67-2 phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside 

Downstream Products

• 664316-68-1 (2S,3R,4R,5R,6R)-3-Azido-6-azidomethyl-4,5-bis-benzyloxy-2-phenylsulfanyl-tetrahydro-pyran 
• 864862-12-4 (1S,3S,4S,6S)-1-O-(2',6'-azido-2',6'-deoxy-3',4'-di-O-benzyl-α-D-glucopyranosyl)-4,6-diazido-cyclohexane-1,3-diol 
• 864862-13-5 (1R,3R,4R,6R)-1-O-(2',6'-azido-2',6'-deoxy-3',4'-di-O-benzyl-α-D-glucopyranosyl)-4,6-diazido-cyclohexane-1,3-diol 
• 663938-12-3 phenyl 2,6-diazido-2,6-dideoxy-1-thio-β-D-glucopyranoside 

Relevant articles and documents

Synthesis of a library of stereo- and regiochemically diverse aminoglycoside derivatives

A library of forty modified aminoglycosides was prepared in which the configuration and regiochemistry of two or three rings was widely varied. The library was based around three core ring systems: the 2-deoxystreptamine ring system found in the natural products, and both enantiomers of (1R*,2R*,4R*,5R*)-2,5-diamino-cyclohexane-1,4-diol and (1R*,3R*,4R*,6R*)-4,6-diaminocyclohexane-1,3-diol. In each case, the core was modified by glycosylation with one or two sugar rings. The absolute configuration of the sugar substituents (D or L), the configuration of the anomeric centres (α or β), and the regiochemical arrangement of the amine(s) were varied. The Royal Society of Chemistry 2005.