Cas 86494-67-9,{RuH(CO)(C6H5P(OC2H5)2)4}(1+)*B(C6H5)4(1-) = {RuH(CO)(C6H5P(OC2H5)2)4}B(C6H5)4

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Product Name: {RuH(CO)(C₆H₅P(OC₂H₅)2)4}⁽¹⁺⁾*B(C₆H₅)4^(1-) = {RuH(CO)(C₆H₅P(OC₂H₅)2)4}B(C₆H₅)4
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CAS NO:86494-67-9
Molecular Formula:
Molecular Weight: 1242.13
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: {RuH(CO)(C₆H₅P(OC₂H₅)2)4}⁽¹⁺⁾*B(C₆H₅)4^(1-) = {RuH(CO)(C₆H₅P(OC₂H₅)2)4}B(C₆H₅)4(CAS DataBase Reference)
NIST Chemistry Reference: {RuH(CO)(C₆H₅P(OC₂H₅)2)4}⁽¹⁺⁾*B(C₆H₅)4^(1-) = {RuH(CO)(C₆H₅P(OC₂H₅)2)4}B(C₆H₅)4(86494-67-9)
EPA Substance Registry System: {RuH(CO)(C₆H₅P(OC₂H₅)2)4}⁽¹⁺⁾*B(C₆H₅)4^(1-) = {RuH(CO)(C₆H₅P(OC₂H₅)2)4}B(C₆H₅)4(86494-67-9)

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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
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Hazardous Substances Data: 86494-67-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 86494-67-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,4,9 and 4 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 86494-67:
(7*8)+(6*6)+(5*4)+(4*9)+(3*4)+(2*6)+(1*7)=179
179 % 10 = 9
So 86494-67-9 is a valid CAS Registry Number.

86494-67-9Upstream product

86494-67-9Downstream Products

86494-67-9Relevant academic research and scientific papers

T1 Values in Hydride and New Molecular Hydrogen Phosphite Complexes of Comparable Structure

Antoniutti, Stefano,Albertin, Gabriele,Amendola, Paola,Bordignon, Emilio

, p. 229 - 230 (1989)

The molecular hydrogen complexes 2-H2)4>BPh4 (M = Fe, Ru, Os) and dihydride species 4>BPh4 have been prepared and T1 measurements for H(1-) and η2-H2 resonances give T1 100 ms f

Molecular hydrogen complexes. Preparation and reactivity of new ruthenium(II) and osmium (II) derivatives and a comparison along the iron triad

Amendola, Paola,Antoniutti, Stefano,Albertin, Gabriele,Bordignon, Emilio

, p. 318 - 324 (2008/10/08)

Molecular hydrogen complexes [MH(η2-H2)P4]BF4 [M = Ru, Os; P = PhP(OEt)2, P(OEt)3, P(OMe)3] were prepared by allowing the MH2P4 hydrides to react with HBF4·Et2O at -80°C in ethanol or diethyl ether. Their characterization by variable-temperature 1H and 31P NMR data, T1 measurements, and JHD values is reported. The influence of the phosphite ligand and the central metal (Fe, Ru, Os) on the properties of the complexes is also discussed. Monohydrido complexes of the type [MHLP4]BPh4 [L = CO, 4-CH3C6H4NC, 4-CH3C6H4CN; P = PhP(OEt)2, P(OEt)3] were obtained by substitution of dihydrogen with the appropriate ligand. The reactions of arenediazonium cations with the molecular hydrogen and dihydride RuH2P4 complexes were examined, and the syntheses of pentacoordinate [Ru(ArN=NH)P4](BPh4)2 and [Ru(ArN2)P4]BPh4 complexes and octahedral [RuH-(ArN=NH)P4]BPh4 and [Ru(ArN=NH)2P4](BPh4)2 derivatives were achieved. The characterization of the complexes by IR and 1H and 31P NMR spectra is reported.

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