864949-39-3Relevant academic research and scientific papers
Formal anti-carbopalladation reactions of non-activated alkynes: Requirements, mechanistic insights, and applications
Pawliczek, Martin,Schneider, Tobias F.,Maa?, Christian,Stalke, Dietmar,Werz, Daniel B.
supporting information, p. 4119 - 4123 (2015/03/30)
Formal anti-carbopalladation reactions of Cpound;C triple bonds are uncommon, but highly useful transformations. Alkynes can be designed to give anti-carbopalladation products. Prerequisite is the exclusion of other reaction pathways to provoke the cis-trans isomerization of the syn-carbopalladation intermediate. Detailed mechanistic studies of this crucial step by experimental and computational means were performed. Application of an intramolecular version for the synthesis of oligocyclic compounds and substituted dibenzofurans is also described.
Rh(I)-catalyzed Pauson-Khand reaction and cycloisomerization of allenynes: Selective preparation of monocyclic, bicyclo[m.3.0], and bicyclo[5.2.0] ring systems
Mukai, Chisato,Inagaki, Fuyuhiko,Yoshida, Tatsunori,Yoshitani, Katsuya,Hara, Yasuyuki,Kitagaki, Shinji
, p. 7159 - 7171 (2007/10/03)
Rhodium(I)-catalyzed PKR of allenynes was found to be applicable for constructing azabicyclo[5.3.0]decadienone as well as oxabicyclo[5.3.0] decadienone frameworks. In addition, a reliable procedure for constructing a 10-monosubstituted bicyclo[5.3.0]deca-
