86509-88-8

Basic information

• Product Name: C₈H₉S
• Synonyms: C₈H₉S
• CAS NO: 86509-88-8
• Molecular Weight: 137.225
• Mol File: 86509-88-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₈H₉S(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₉S(86509-88-8)
• EPA Substance Registry System: C₈H₉S(86509-88-8)

Safety Data

• Hazardous Substances Data: 86509-88-8(Hazardous Substances Data)

Upstream product

• 345937-14-6 bis-<2-(methylthio)benzyl> oxalate 

Relevant articles and documents

Intramolecular Reactions of o-Alkoxy- and o-Alkylthio-benzyl Radicals

We report new gas-phase reactions of o-substituted benzyl radicals produced by flash vacuum pyrolysis of 2,3-dihydro-1,3,2-benzoxazaphosph(V)oles (4)-(6), dibenzyl sulphone (8), and dibenzyl oxalates (9)-(11).Both o-ethoxy- and o-methoxy-benzyl radicals rearrange to o-tolualdehyde via intramolecular hydrogen transfer, as shown by experiments using 2-methoxybenzyl radicals. o-Methylthiobenzyl radicals do not give the corresponding thioaldehyde, but produce a mixture of benzocyclobutene and isomeric dihydrobenzothiophens by novel rearrangement reactions. o-Ethylthio- and o-propylthio-benzyl radicals give o-methylstyrene and o-propenyltoluenes respectively as major products.