86519-33-7Relevant articles and documents
PH-Responsive N-heterocyclic carbene copper(i) complexes: Syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide
Wang, Wenlong,Zhang, Guodong,Lang, Rui,Xia, Chungu,Li, Fuwei
, p. 635 - 640 (2013/03/29)
A pH-controlled monophasic/biphasic switchable system has been developed as a green and novel strategy for homogeneous catalyst recycling, which has been successfully applied to the Cu-NHC-catalyzed carboxylation of organoboronic esters and benzoxazole with carbon dioxide. Additionally, the present strategy could also be extended to the Ag-NHC-catalyzed carboxylation of terminal alkyne. The tertiary amine-functionalized catalysts could be used for at least four times with a slight loss of activity.
Fluorophore tagged cross-coupling catalysts
Sashuk, Volodymyr,Schoeps, Dirk,Plenio, Herbert
supporting information; experimental part, p. 770 - 772 (2009/07/10)
Fluorophore tagged N-heterocyclic carbenes and the derived (NHC)Pd(allyl)Cl complexes were synthesized and the fluorescence signal was used to follow the course of a Suzuki coupling reaction. The Royal Society of Chemistry.
Water-soluble propofol analogues with intravenous anaesthetic activity
Cooke, Andrew,Anderson, Alison,Buchanan, Kirsteen,Byford, Alan,Gemmell, David,Hamilton, Niall,McPhail, Petula,Miller, Susan,Sundaram, Hardy,Vijn, Peter
, p. 927 - 930 (2007/10/03)
Propofol (2,6-diisopropylphenol) is a widely used intravenous anaesthetic that is formulated as an emulsion since it lacks water solubility. We report a range of water-soluble analogues of propofol, containing a para-alkylamino substituent, which retain good intravenous anaesthetic activity in rodents.
Benzylpyrimidine synthesis and intermediates
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, (2008/06/13)
2,4-Diamino-5-(4-amino- and 4-loweralkylamino-3,5-disubstitutedbenzyl)pyrimidines are prepared by a novel method using 2,6-disubstituted anilines and pyrimidines. Several novel intermediates are involved.