865308-23-2

Upstream product

• 118740-38-8 chloro(α,α-dimethylbenzyl)dimethylsilane 
• 865308-25-4 (2R,3R,4E)-2-[2-(tert-butyldimethylsiloxy)ethyl]hex-4-ene-1,2,3-triol 
• 1027938-82-4 cumyldimethylsilyl trifluoromethanesulfonate 
• 865308-22-1 [2-(1R,2E)-1-(cumyldimethylsiloxy)but-2-enyl](2R)-2,4-dihydroxybutyl acetate 
• 865308-30-1 (E)-(2S,3R)-2-Benzyloxy-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-[dimethyl-(1-methyl-1-phenyl-ethyl)-silanyloxy]-hex-4-enoic acid methyl ester 
• 865308-20-9 (E)-(2R,3R)-2-Benzyloxy-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-[dimethyl-(1-methyl-1-phenyl-ethyl)-silanyloxy]-hex-4-en-1-ol 
• 865308-21-0 (E)-(R)-2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3-[dimethyl-(1-methyl-1-phenyl-ethyl)-silanyloxy]-hex-4-ene-1,2-diol 
• 865308-24-3 (2R,3R,4E)-2-(benzyloxy)-2-[2-(tert-butyldimethylsiloxy)ethyl]hex-4-ene-1,3-diol 
• 865308-26-5 (2R,3R,4E)-2-(2-[t-butyldimethylsiloxy]ethyl)-2,3-dihydroxyhex-4-enyl acetate 
• 886588-97-2 (2R,4E)-2-(2-[t-butyldimethylsiloxy]ethyl)-3-(cumyldimethylsiloxy)-2-hydroxyhex-4-enyl acetate 
• 865308-33-4 (2R,3R,4E)-2-(2-[t-butyldimethylsiloxy]ethyl)-3-(cumyldimethylsiloxy)-2-hydroxyhex-4-enyl acetate 

Downstream Products

• 865308-34-5 ((1S,5S,7R)-7-(cumyldimethylsiloxy)-5-methyl-4,8-dioxabicyclo[3.2.1]octyl)formaldehyde 
• 865308-35-6 (1S,5R,6R)-6-(cumyldimethylsiloxy)-1-methyl-2,8-dioxa-5-vinylbicyclo[3.2.1]octane 
• 865308-27-6 ((1R,5S,7R)-7-(cumyldimethylsiloxy)-5-methyl-4,8-dioxabicyclo[3.2.1]octyl)methanol 

Relevant academic research and scientific papers

Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

An efficient method for the synthesis of (+)-buergerinin F is established via the enantioselective aldol reaction of a tetra-substituted ketene silyl acetal with crotonaldehyde, followed by intramolecular Wacker-type ketalization. The Royal Society of Chemistry 2005.