865355-87-9Relevant academic research and scientific papers
Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: Rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides
Shintani, Ryo,Duan, Wei-Liang,Nagano, Takashi,Okada, Atsushi,Hayashi, Tamio
, p. 4611 - 4614 (2007/10/03)
(Chemical Equation Presented) Two is better than one: Novel chiral phosphine - olefin ligands 1 a and 1 b act as bidentate ligands with some transition metals and have proved to be highly effective in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides with high enantio-selectivity (see scheme).
