86539-31-3Relevant articles and documents
Isolation of a Highly Persistent Diphosphanyl Radical: The Phosphorus Analogue of a Hydrazyl
Loss, Sandra,Magistrato, Alessandra,Cataldo, Laurent,Hoffmann, Stefan,Geoffroy, Michel,Roethlisberger, Ursula,Gruetzmacher, Hansjoerg
, p. 723 - 726 (2007/10/03)
Stable for at least one week below -30°C: crystals of 1, the first highly persistent diphosphanyl radical, have been isolated and characterized. This phosphorus-centered radical exhibits hyperfine coupling whose anisotropy is considerably larger than that for well-established nitrogen radicals (hydrazyls nitroxides). This feature is of potential interest for studies of fast molecular movements. Mes =2,4,6-tBu3C6H2.
Nucleophilic Attack of a Phosphorus-Phosphorus Double Bond
Cowley, A. H.,Pakulski, M. K.
, p. 1491 - 1492 (2007/10/02)
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