86544-90-3

Upstream product

• 16844-07-8 meso-2,3-dimethylsuccinic anhydride 
• 98-59-9 p-toluenesulfonyl chloride 
• 28763-09-9 (2R,3R)-3-Amino-2-methyl-butyric acid methyl ester 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 
• 86544-86-7 (3R,6S)-3,4,5,6-Tetramethyl-2-(toluene-4-sulfonyl)-3,6-dihydro-2H-[1,2]thiazine 1-oxide 
• 18265-39-9 (E,E)-3,4-dimethylhexa-2,4-diene 
• 86544-88-9 4-Methyl-N-((E)-(1R,2S)-1,2,3-trimethyl-pent-3-enyl)-benzenesulfonamide 
• 917-54-4 methyllithium 
• 5866-20-6 trans-2,3-dimethylsuccinic anhydride 
• 28763-09-9 (2R,3S)-3-Amino-2-methyl-butyric acid methyl ester 
• 86544-86-7 (3R,6R)-3,4,5,6-Tetramethyl-2-(toluene-4-sulfonyl)-3,6-dihydro-2H-[1,2]thiazine 1-oxide 
• 2417-88-1 (E,Z)-3,4-dimethylhexa-2,4-diene 
• 86544-88-9 4-Methyl-N-((E)-(1R,2R)-1,2,3-trimethyl-pent-3-enyl)-benzenesulfonamide 

Relevant academic research and scientific papers

NATURAL PRODUCT SYNTHESIS VIA CYCLOADDITIONS WITH N-SULFINYL DIENOPHILES

Diels-Alder cycloadducts derived from N-sulfinyl dienophiles have been used for stereospecific preparation of acyclic unsaturated amines and in stereospecific syntheses of threo-sphingosine (31) and erythro sphingosine (32).Methodology based upon these cy

A METHOD FOR DIASTEREOSELECTIVE SYNTHESIS OF UNSATURATED ACYCLIC AMINES

Diels-Alder adducts of dienes and N-sulfinyltoluenesulfonamide can be used in synthesis of homoallylic amine derivatives having predictable stereochemistry and double bond geometry.