865448-72-2Relevant academic research and scientific papers
Synthesis of triphenylamine (TPA) dimers and applications in cell imaging
Yuan, Yang,Yin, Pei,Wang, Tao,Yang, Zengming,Yin, Weidong,Zhang, Shaoxiong,Qi, Chunxuan,Hengchang, Ma
, (2019/11/26)
A variety of triphenylamine (TPA) are shown to undergo C–C bond formation using quinone-based chloranil/H+ reagent as the metal free oxidative system to afford triphenylamine dimers very conveniently. Then, TPA dimers have been further converte
Two-dimensional dual-pore covalent organic frameworks obtained from the combination of two: D 2h symmetrical building blocks
Tian, Yuan,Xu, Shun-Qi,Qian, Cheng,Pang, Zhong-Fu,Jiang, Guo-Fang,Zhao, Xin
supporting information, p. 11704 - 11707 (2016/10/04)
A strategy to construct covalent organic frameworks (COFs) bearing two different kinds of pores has been developed, by which two dual-pore COFs were fabricated through the condensation reactions of two D2h symmetrical building blocks. The COFs exhibit good adsorption capacities for CO2 and H2.
Solution-processed thermally stable amorphous films of small molecular hole injection/transport bi-functional materials and their application in high efficiency OLEDs
Zhao, Xiaoming,Wang, Shirong,You, Jing,Zhang, Yuteng,Li, Xianggao
supporting information, p. 11377 - 11384 (2015/11/11)
A series of novel triphenylamine-based small molecular hole transport materials (HTMs) are reported for solution processed organic light-emitting devices (OLEDs). The character of this series of HTMs, denoted as TPD(BTPA)n (n = 1, 2, 4), is connecting the flexible moieties of butadiene bridged triphenylamine (BTPA) to N,N,N′,N′-tetraphenyl-[1,1′-biphenyl]-4,4′-diamine (TPD). The glass transition temperature and crystallization temperature (Tg and Tc) showed a proportional relationship with the number of BTPA moieties. The Tg value of TPD(BTPA)4 can be up to 125.5 °C, which is higher than most of the reported small molecular HTMs (Tg: 54-116 °C). The TPD(BTPA)4 spincoated film showed an outstanding thermal stability which remained amorphous even when annealed at 110 °C, for 48 h. This indicated that the breaking of the planar molecular structure with BTPA moieties can suppress intermolecular stacking. The solution processed OLEDs with 8-hydroxyquinoline aluminum (Alq3) as emission and electron transport layers showed high stability at high operation current (>400 mA cm-2). The OLED with TPD(BTPA)4 achieved a maximum current efficiency of 5.83 cd A-1 (at the operation current density > 400 mA cm-2), which is higher than the maximum current efficiency of most evaporation and solution processed OLEDs in identical structures.
Electrophilic aromatic substitution with diacyl imidazolium
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Page/Page column 23; sheet 3, (2010/02/17)
Polyimidazoline molecules and methods of making them are provided. A representative polyimidazoline has a structure: wherein: X is trifluoroacetyl or trifluoromethanesulfonyl; R1, R2, and R3 are each independently selected from a hydrogen, C1-C4 alkyl, C3-C7 cyclic alkyl, C1-C4 alkoxy, alcohol, and halogen; and n is 1 to 3.
