86549-25-9

Basic information

• Product Name: 5-Hexen-1-ol, 3,3-dimethyl-, 4-methylbenzenesulfonate
• CAS NO: 86549-25-9
• Molecular Formula: C15H22O3S
• Molecular Weight: 282.404
• Mol File: 86549-25-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 5-Hexen-1-ol, 3,3-dimethyl-, 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-1-ol, 3,3-dimethyl-, 4-methylbenzenesulfonate(86549-25-9)
• EPA Substance Registry System: 5-Hexen-1-ol, 3,3-dimethyl-, 4-methylbenzenesulfonate(86549-25-9)

Safety Data

• Hazardous Substances Data: 86549-25-9(Hazardous Substances Data)

Upstream product

• 77290-88-1 3,3-dimethylhex-5-enoic acid 
• 75277-81-5 methyl 3,3-dimethyl-5-hexenoate 
• 35466-83-2 allyl methyl carbonate 
• 86549-23-7 ethyl 3,3-dimethylhex-5-enoate 
• 32119-46-3 diethyl 2-(1,1-dimethylbut-3-enyl)-propanedioate 
• 6802-75-1 diethyl isopropylidenemalonate 
• 86549-24-8 3,3-dimethylhex-5-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Intramolecular Organocatalytic [3+2] Dipolar Cycloaddition: Stereospecific Cycloaddition and the Total Synthesis of (±)-Hirsutene

A testing ground for cyclopentannulation strategies: the triquinane natural product hirsutene is obtained through the intramolecular organocatalytic [3+2] cycloaddition of the 1,7-enyne (E)-1. The cycloaddition is stereospecific: reaction of the correspon

Nickel-Catalyzed Reductive Allylation of Tertiary Alkyl Halides with Allylic Carbonates

The construction of all C(sp3) quaternary centers has been successfully achieved under Ni-catalyzed cross-electrophile coupling of allylic carbonates with unactivated tertiary alkyl halides. For allylic carbonates bearing C1 or C3 substituents, the reaction affords excellent regioselectivity through the addition of alkyl groups to the unsubstituted allylic carbon terminus. The allylic alkylation method also exhibits excellent functional-group compatibility, and delivers the products with high E selectivity.