865533-76-2Relevant academic research and scientific papers
PROCESSES FOR HIGHLY ENANTIO-AND DIASTEREOSELECTIVE SYNTHESIS OF ACYCLIC EPOXY ALCOHOLS AND ALLYLIC EPOXY ALCOHOLS
-
Page/Page column 70-71, (2008/06/13)
The inventive subject matter relates to novel processes for making an epoxy alcohol from an aldehyde, comprising the steps of: (a) adding (i) an organozinc compound or (ii) divinylzinc compound and an diorganozinc compound to said aldehyde in the presence
Highly enantio- and diasfereoselective one-pot synthesis of acyclic epoxy alcohols with three contiguous stereocenters
Lurain, Alice E.,Maestri, Aaron,Kelly, Ann Rowley,Carroll, Patrick J.,Walsh, Patrick J.
, p. 13608 - 13609 (2007/10/03)
Two highly enantio- and diastereoselective one-pot procedures for the synthesis of epoxy alcohols with up to three contiguous stereocenters are reported. Route one involves asymmetric addition of an alkylzinc reagent to an enal followed by diastereoselect
