865622-63-5

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 620987-55-5 (3R,5R)-5-((1S)-1-hydroxyethyl)-2-methoxyoxolan-3-yl 6-methoxy-2-prop-2-enylbenzoate 
• 73707-65-0 (3R,4R,5R,6S)-6-methyl-2-oxo-4,5-diphenylcarbonyloxy-3H-4,5,6-trihydropyran-3-yl benzoate 
• 73-34-7 L-rhamnose 
• 73-34-7 L-rhamnose 
• 325172-28-9 2-allyl-6-methoxy-benzoic acid 
• 20031-16-7 L-Rhamnono-1,4-lactone 
• 81644-86-2 2,3,5-tri-O-benzoyl-L-rhamnono-1,4-lactone 
• 75721-93-6 2,5-di-O-benzoyl-3,6-dideoxy-L-arabino-hexono-1,4-lactone 
• 620987-54-4 (3R,5R)-5-((1S)-1-hydroxyethyl)-2-oxo-3,4,5-trihydrofuryl 6-methoxy-2-prop-2-enylbenzoate 
• 69992-12-7 (3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyl-3H-4,5,6-trihydropyran-2-one 
• 73679-22-8 (3R,5R,6S)-6-methyl-3-hydroxy-5-(hydroxyethyl)-3,4,5-trihydrofuran-2-one 

Downstream Products

• 620987-63-5 (3R,5R)-5-((1S)-1-methylbut-3-enyl)-2-methoxyoxolan-3-yl 6-methoxy-2-prop-2-enylbenzoate 
• 620987-65-7 (1S,3R,4S)-1-(2-cyanoethyl)-3-hydroxy-4-methylhept-6-enyl 6-hydroxy-2-prop-2-enylbenzoate 
• 620987-64-6 1-((1E)-2-cyanovinyl)-(1R,3R,4S)-3-hydroxy-4-methylhept-6-enyl 6-hydroxy-2-prop-2-enylbenzoate 
• 620987-56-6 (3R,5R)-5-((1S)-1-methylbut-3-enyl)-2-hydroxyoxolan-3-yl 6-hydroxy-2-prop-2-enylbenzoate 

Relevant academic research and scientific papers

Formal total syntheses of the (-)-salicylihalamides A and B from D-glucose and L-rhamnose

Two formal total syntheses of the (-)-salicylihalamides, based on chiral pool approaches, are reported. D-Glucose and L-rhamnose were used to prepare advanced intermediates 23 and 54, which can be converted in three or four steps, respectively, to the tar

Enantiospecific Formal Total Syntheses of (-)-Salicylihalamides A and B from D-Glucose and L-Rhamnose

(Matrix Presented) Two formal chiral pool syntheses of the (-)-salicylihalamides A and B were achieved from commercially available 1,2,5,6-diacetone-D-glucose and L-rhamnose.