86590-57-0

Basic information

• Product Name: 1-(Adamant-1-yl)-2-phenyl-1-(pyrid-4-yl)-ethan
• CAS NO: 86590-57-0
• Molecular Weight: 317.474
• Mol File: 86590-57-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(Adamant-1-yl)-2-phenyl-1-(pyrid-4-yl)-ethan(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(Adamant-1-yl)-2-phenyl-1-(pyrid-4-yl)-ethan(86590-57-0)
• EPA Substance Registry System: 1-(Adamant-1-yl)-2-phenyl-1-(pyrid-4-yl)-ethan(86590-57-0)

Safety Data

• Hazardous Substances Data: 86590-57-0(Hazardous Substances Data)

Upstream product

• 2502-99-0 (E)-4-(4-chlorostyryl)pyridine 
• 5097-93-8 trans-4-styrylpyride 
• 768-90-1 1-Adamantyl bromide 

Relevant articles and documents

Electrochemical Adamantylation of Styrylpyridines

The reaction between electrochemically generated anion radicals of the 4-(4-styryl)-pyridines 1-6 and 1-bromoadamantane gives, in solvents of low proton availability as N,N-dimethylformamide via an electron transfer in solution and formation of 1-adamantyl-radicals, monoadamantylated pyrid-4-yl-phenylethanes.The major product results from an anion radical/radical-coupling in the 2(β)-next the 1(α)-position.A competing pathway of the electrohydroadamantylation is the hydrogeneration of the -CH=CH-double bond, whose importance increases with the water content of the solvent.Based on cyclic-voltammetric evidence and product distribution, the mechanism of the reductive coupling of 1-6 in the presence of 1-bromoadamantane is discussed in terms of indirect electrolysis.