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Untersuchungen ueber gespannte cyclische Acetylene, VIII Hydrierung winkelgespannter Siebenring-Acetylene mit Alkoholen
Krebs, Adolf,Colberg, Horst
, p. 2007 - 2014 (2007/10/02)
The strained seven-membered cycloalkyne 1a reacts at room temperature with methanol, 2-propanol, and benzyl alcohols, respectively, to give the alkene 2a and the corresponding carbonyl compounds.The H/D-isotope effects were investigated and a mechanism is proposed for this reaction on the basis of the rate law.
