866006-98-6Relevant articles and documents
Silatropic carbonyl ene cyclizations in the synthesis of pseudosugars and hydroxylated piperidines
Robertson, Jeremy,Stafford, Petra M.,Bell, Stephen J.
, p. 7133 - 7148 (2007/10/03)
We describe two applications of silicon-tethered thermal allyl transfer reactions of α-silyloxyaldehydes; formally, these processes can be regarded as silatropic carbonyl ene reactions in which the silicon tether is transferred to the aldehyde oxygen conc