86602-25-7

Basic information

• Product Name: (Z)-1-chloro-2-(4-chlorophenylthio)-1-phenylethene
• CAS NO: 86602-25-7
• Molecular Weight: 281.205
• Mol File: 86602-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-chloro-2-(4-chlorophenylthio)-1-phenylethene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-chloro-2-(4-chlorophenylthio)-1-phenylethene(86602-25-7)
• EPA Substance Registry System: (Z)-1-chloro-2-(4-chlorophenylthio)-1-phenylethene(86602-25-7)

Safety Data

• Hazardous Substances Data: 86602-25-7(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 86602-23-5 (E)-(2-chloro-1-phenylvinyl)(4-chlorophenyl)sulfane 

Downstream Products

• 100716-73-2 4-chlorophenyl 2-phenylethyl sulphone 
• 31599-09-4 (Z)-1-chloro-2-(4-chlorophenylsulphonyl)-1-phenylethene 

Relevant articles and documents

Addition of 4-Chlorobenzenesulphenyl Chloride to 3-Methylbut-1-yne, Hex-1-yne, and Phenylacetylene: Isomerisation and Hydrolysis of the Adducts

The addition of (4-ClC6H4SCl, (2), to RCH(*)CH, (1; R=Pri, Bun), gives (E)-4-ClC6H4(R)C(*)C(H)Cl, (E)-(3), and (E)-4-ClC6H4(H)C(*)C(R)Cl, (E)-(4) in a fixed ratio; the addition to (1; R=Ph) gives regiospecifically (E)-(3; R=Ph) in ethyl acetate, but different proportions of (E)-(3) and (E)-(4) (R=Ph), in chloroform, sym-tetrachloroethane, and acetic acid.With an excess of the sulphenyl chloride (2), (E)-(3) and (E)-(4) isomerize to (Z)-(4) (same R).The sulphuric-acid catalysed hydrolysis of (E)-(3; R=Pri, Bun, Ph) gives α-chloroketones RCOCH2Cl(5) (same R).The (E)-(4) isomers do not hydrolyse.