866021-85-4

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 866021-79-6 [(2R,6S)-6-(2-oxoethyl)tetrahydropyran-2-yl]acetic acid ethyl ester 
• 866021-62-7 ((2R,6S)-6-allyltetrahydropyran-2-yl)acetic acid ethyl ester 
• 866021-67-2 (2S,5S,7S)-1-benzyloxy-7-(tert-butyldimethylsilanyloxy)-8-{(2S,6R)-6-[2-(tert-butyldimethylsilanyloxy)ethyl]tetrahydropyran-2-yl}-5-hydroxy-2-methyloctan-3-one 
• 866022-18-6 (2R,6S)-2-[2-(tert-butyldimethylsilanyloxy)ethyl]-6-[(S)-2-(tert-butyldimethylsilanyloxy)pent-4-enyl]tetrahydropyran 
• 866021-64-9 (R)-3-(tert-butyldimethylsilanyloxy)-4-{(2S,6R)-6-[2-(tert-butyldimethylsilanyloxy)ethyl]tetrahydropyran-2-yl}butyraldehyde 
• 866021-63-8 [(2R,6S)-6-((S)-2-hydroxypent-4-enyl)tetrahydropyran-2-yl]acetic acid ethyl ester 
• 866021-82-1 (S)-1-[(2S,6R)-6-(2-hydroxyethyl)tetrahydropyran-2-yl]pent-4-en-2-ol 

Downstream Products

• 866021-69-4 (4R,6R)-4-((S)-2-benzyloxy-1-methylethyl)-6-((R)-2-(tert-butyldimethylsilanyloxy)-3-{(2S,6R)-6-[2-(tert-butyldimethylsilanyloxy)ethyl]tetrahydropyran-2-yl}propyl)-2,2-dimethyl-[1,3]dioxane 
• 866021-57-0 C₆₀H₁₁₀O₁₂Si₃ 
• 866022-14-2 C₆₀H₁₁₀O₁₂Si₃ 
• 866022-15-3 C₆₀H₁₀₈O₁₂Si₃ 

Relevant academic research and scientific papers

Toward the synthesis of spirastrellolide A: Construction of two C 1-C25 diastereomers containing the BC-spiroacetal

(Chemical Equation Presented) Stereocontrolled syntheses of two possible C1-C25 diastereomers of spirastrellolide A containing the cis-disubstituted tetrahydropyran and [6,6]-spiroacetal are reported, exploiting boron-mediated asymme