866022-07-3

Upstream product

• 866021-72-9 benzoic acid (1S,3R,4S)-4-hydroxy-4-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,3-dimethyl-2-oxobutyl ester 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 866021-71-8 (4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 
• 866022-02-8 (S)-1-((4S,5S)-5-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 866022-05-1 tert-butyl-[(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-ylmethoxy]dimethylsilane 
• 866022-06-2 [(4S,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol 
• 108817-97-6 (4R,5S)-5-tert-butyldimethylsilyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 

Downstream Products

• 866022-17-5 C₆₀H₁₀₈O₁₂Si₃ 
• 866022-15-3 C₆₀H₁₀₈O₁₂Si₃ 
• 866022-16-4 C₆₀H₁₁₀O₁₂Si₃ 
• 866022-14-2 C₆₀H₁₁₀O₁₂Si₃ 
• 866021-58-1 C₆₀H₁₁₀O₁₂Si₃ 
• 866021-57-0 C₆₀H₁₁₀O₁₂Si₃ 
• 866022-13-1 (S)-4-{(4S,5R)-5-[(1S,2S)-3-(4-methoxybenzyloxy)-1-(tert-butyldimethylsilanyloxy)-2-methylpropyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-4-methoxybutan-1-ol 
• 866021-61-6 (S)-4-{(4S,5R)-5-[(1S,2S)-3-(4-methoxybenzyloxy)-1-(tert-butyldimethylsilanyloxy)-2-methylpropyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-4-methoxybutyraldehyde 
• 866022-09-5 tert-butyl-{(1S,2S)-3-(4-methoxybenzyloxy)-1-[(4R,5S)-5-((S)-1-methoxybut-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropoxy}dimethylsilane 

Relevant academic research and scientific papers

Toward the synthesis of spirastrellolide A: Construction of two C 1-C25 diastereomers containing the BC-spiroacetal

(Chemical Equation Presented) Stereocontrolled syntheses of two possible C1-C25 diastereomers of spirastrellolide A containing the cis-disubstituted tetrahydropyran and [6,6]-spiroacetal are reported, exploiting boron-mediated asymme