866044-17-9

Upstream product

• 5779-95-3 3,5-dimethylbenzaldehyde 
• 866044-13-5 (R,R)-1,2-diazido-1,2-bis(3,5-dimethylphenyl)ethane 
• 196605-90-0 (S,S)-(+)-1,2-bis(3,5-dimethylphenyl)ethane-1,2-diol 
• 13863-27-9 (E)-1,2-bis(3,5-dimethylphenyl)ethene 
• 27129-86-8 1-bromomethyl-3,5-dimethylbenzene 
• 52988-36-0 triphenyl(3,5-dimethylbenzyl)phosphonium bromide 

Relevant academic research and scientific papers

Chiral bis(N-sulfonylamino)phosphine- and TADDOL-phosphite-oxazoline ligands: Synthesis and application in asymmetric catalysis

A series of N,P-ligands has been prepared, containing a chiral oxazoline ring and as a second chiral unit a bis(N-sulfonylamino)phosphine group embedded in a diazaphospholidine ring or a cyclic phosphite group derived from TADDOL. These modular ligands are readily synthesized from chiral amino alcohols and chiral 1,2-diamines or TADDOLs. Palladium and iridium complexes derived from these ligands were found to be efficient catalysts for enantioselective allylic alkylation and olefin hydrogenation, respectively.