86608-70-0

Basic information

• Product Name: 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
• Synonyms: 2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;2-(1,3)-DIOXOLANE-2-YL) ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSP;Phosphonium, 2-(1,3-dioxolan-2-yl)ethyltriphenyl-, bromide;[2-(1,3-dioxalan-2-yl)ethyl]triphenylphosphonium bromide;2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide,97%;2-(1,3-Dioxolan-2-yl)ethyltrip;Phosphonium,[2-(1,3-dioxolan-2-yl)ethyl]triphenyl-, bromide (1:1)
• CAS NO: 86608-70-0
• Molecular Formula: Br*C₂₃H₂₄O₂P
• Molecular Weight: 443.31
• EINECS: 404-940-6
• Product Categories: Dioxanes & Dioxolanes;Dioxolanes;Phosphonium Compounds;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction;C-C Bond Formation;Olefination;Wittig Reagents
• Mol File: 86608-70-0.mol
• Article Data: 4

Chemical Properties

• Melting Point: 144-146 °C(lit.)
• Appearance: /solid
• Solubility: soluble in Methanol
• BRN: 5209374
• CAS DataBase Reference: 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)
• EPA Substance Registry System: 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide(86608-70-0)

Safety Data

• Hazard Codes: Xn
• Statements: 22-33-41-52/53
• Safety Statements: 22-26-39-61
• WGK Germany: 2
• F: 3
• Hazardous Substances Data: 86608-70-0(Hazardous Substances Data)

Usage

Chemical Properties

Pale yellow powder

Uses

Different sources of media describe the Uses of 86608-70-0 differently. You can refer to the following data:
1. suzuki reaction
2. Reactant for:Wittig olefinationPreparationof ligands for histamine receptor binding with H3/H4 subtype selectivityPreparation of dual inhibitors of phosphodiesterase-4 and serotonin reuptake

InChI:InChI=1/C23H24O2P.BrH/c1-4-10-20(11-5-1)26(21-12-6-2-7-13-21,22-14-8-3-9-15-22)19-16-23-24-17-18-25-23;/h1-15,23H,16-19H2;1H/q+1;/p-1

Upstream product

• 18742-02-4 2-bromo-2-(2-ethyl)dioxolane 
• 603-35-0 triphenylphosphine 

Downstream Products

• 866141-89-1 (2S,4R)-4-t-butyldimethylsilyloxy-2-[3-(1,3-dioxolan-2-yl)prop-1-en-1-yl]-1-(4-methylphenylsulfonyl)pyrrolidine 
• 850656-41-6 [(2R,3S,5S)-5-(2-Benzyloxy-ethyl)-2-((Z)-3-[1,3]dioxolan-2-yl-propenyl)-tetrahydro-furan-3-yloxy]-tert-butyl-dimethyl-silane 
• 667909-36-6 4-((E)-3-[1,3]Dioxolan-2-yl-propenyl)-benzoic acid methyl ester 
• 667909-38-8 2-((E)-3-[1,3]Dioxolan-2-yl-propenyl)-benzoic acid methyl ester 
• 406225-21-6 (Z)-4-(3-(1,3-dioxolan-2-yl)prop-1-enyl)-1-trityl-1H-imidazole 
• 124555-52-8 4-(2,5-dimethoxyphenyl)-3-butenal ethylene acetal 
• 1225448-51-0 (2S,4R)-4-(tert-butyldimethylsilyloxy)-1-benzyl-2-[3-(1,3-dioxolan-2-yl)propenyl]-2-pentylpyrrolidine 
• 741269-11-4 benzyl 2-[3-(1,3-dioxolan-2-yl)-1-propenyl]pyrrolidine-1-carboxylate 

Relevant articles and documents

Stereoselective synthesis of 3-oxygenated-ds-dialkyl-2,5-substituted tetrahydrofurans from cyclohexadienediols

(Chemical Equation Presented) The 3-oxygenated-cis-dialkyl-2,5-substituted tetrahydrofuran system, present in several natural products, was prepared with good selectivity by acidic cyclization of 5-alkene-1,2,4-triol derivatives. The starting alkenol was

SYNTHESIS OF A PHOTOSYNTHETIC MODEL COMPOUND WITH A LONG ALKYL CHAIN AND ITS INCORPORATION INTO BOVINE SERUM ALBUMIN

Quinone-linked porphyrin 1 having a long alkyl chain was synthesized and fixed it into bovine serum albumin (BSA) for getting the information about the effect of protein upon photosynthetic electron transfer.The complex of the reference compound 19 lacking quinone with BSA showed fluorescence, while BSA-1 did not fluoresce at all.