866270-07-7Relevant academic research and scientific papers
Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products
Gentry, Emily C.,Rono, Lydia J.,Hale, Martina E.,Matsuura, Rei,Knowles, Robert R.
supporting information, p. 3394 - 3402 (2018/03/13)
While interest in the synthetic chemistry of radical cations continues to grow, controlling enantioselectivity in the reactions of these intermediates remains a challenge. Based on recent insights into the oxidation of tryptophan in enzymatic systems, we
The diazo route to diazonamide A. Studies on the indole bis-oxazole fragment
Davies, James R.,Kane, Peter D.,Moody, Christopher J.
, p. 7305 - 7316 (2007/10/03)
Various approaches to the indole bis-oxazole fragment of the marine secondary metabolite diazonamide A are described, all of which feature dirhodium(II)-catalyzed reactions of diazocarbonyl compounds in key steps. Thus, 3-bromophenylacetaldehyde is conver
