86632-82-8

Basic information

• Product Name: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol
• Synonyms: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol
• CAS NO: 86632-82-8
• Molecular Weight: 202.251
• Mol File: 86632-82-8.mol

Chemical Properties

• CAS DataBase Reference: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(86632-82-8)
• EPA Substance Registry System: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(86632-82-8)

Safety Data

• Hazardous Substances Data: 86632-82-8(Hazardous Substances Data)

Upstream product

• 125459-22-5 1,2,3,4-tetramethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene 
• 86632-81-7 C₂₄H₂₈O₅ 
• 135456-81-4 (1R,4S,5R,6S)-4,5,6-Trimethoxy-cyclohex-2-enol 
• 74-88-4 methyl iodide 
• 125546-17-0 1,4-dimethoxy-1β,4β,4aβ,9α,9aβ,10α-hexahydro-9,10<1',2'>benzenoanthracene 
• 125459-21-4 2,3-dihydroxy-1,4-dimethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene 
• 135456-73-4 O²,O³,O⁴-trimethyl-L-arabinose diethyl dithioacetal 
• 135456-79-0 (Z)-(2S,3R,4S)-2,3,4-Trimethoxy-6-trimethylsilanyl-hex-5-en-1-ol 
• 135456-80-3 (Z)-(2R,3R,4S)-2,3,4-Trimethoxy-6-trimethylsilanyl-hex-5-enal 
• 135456-75-6 (2R,3S,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3,4-trimethoxy-pentanal 
• 135456-74-5 ((2S,3S,4R)-5,5-Bis-ethylsulfanyl-2,3,4-trimethoxy-pentyloxy)-tert-butyl-dimethyl-silane 
• 135456-76-7 tert-Butyl-((2S,3R,4S)-6,6-dibromo-2,3,4-trimethoxy-hex-5-enyloxy)-dimethyl-silane 
• 135456-77-8 (3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-3,4,5-trimethoxy-1-trimethylsilanyl-hex-1-yne 
• 135456-78-9 (Z)-(3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-3,4,5-trimethoxy-1-trimethylsilanyl-hex-1-ene 

Downstream Products

• 130824-36-1 2α,3β,4β,5α-tetramethoxycyclohex-1α-yl 3',5'-dinitrobenzoate 
• 130824-37-2 2β,3β,4α-trimethoxycyclohex-1α-yl 3',5'-dinitrobenzoate 
• 130824-39-4 1α,2α,3β-trimethoxycyclohex-5b-yl 3',5'-dinitrobenzoate 
• 488-73-3 (+/-)-cyclohexane-1r,2c,3t,4c,5t-pentaol 
• 488-73-3 (1α,2β,3α,4α,5β)-1,2,3,4,5-Cyclohexanpentol 
• 130824-38-3 (1R,2S,3R,4S)-2,3,4-Trimethoxy-cyclohexanol 
• 130824-40-7 (3R,5R)-3,4,5-Trimethoxy-cyclohexanol 
• 130824-35-0 proto-quercitol tetramethyl ether 

Relevant articles and documents

An Approach to Total Synthesis of (+)-Lycoricidine

A convergent synthesis of a protected version of (+)-lycoricidine has been accomplished in 13 steps from L-arabinose.Preparation of the aminocyclitol moiety 50 employed a novel vinylsilane-terminated N-sulfonyliminium ion cyclization of vinylsilane aldehyde 42.Closure of the B-ring using an intramolecular Heck reaction afforded lycoricidine derivative 58.An unexpected cyclization of vinylsilane aldehyde 42 allowed for the stereodivergent preparation of semiprotected conduritols 43 and 45.

A Strategy for Synthesis of Conduritols and Related Cyclitols via Stereodivergent Vinylsilane-Aldehyde Cyclizations

A novel stereospecific and stereodivergent cyclization of vinylsilane-aldehyde 10, derived from L-arabinose, has been used to prepare the scalemic protected conduritols 11 and 12.