866321-70-2Relevant academic research and scientific papers
Half-rotation in a [2]catenane via interconvertible Pd(II) coordination modes
Leigh, David A.,Lusby, Paul J.,Slawin, Alexandra M. Z.,Walker, D. Barney
, p. 4919 - 4921 (2005)
Reaction of a [2]catenane with Pd(OAc)2 binds both macrocycles to the metal, locking them in position; treatment with PdCl2, however, results in coordination of only one ring, producing a half-turn in the relative orientation of the [2]catenane components in both solution and the solid state. The Royal Society of Chemistry 2005.
Selecting topology and connectivity through metal-directed macrocyclization reactions: A square planar palladium [2]catenate and two noninterlocked isomers
Fuller, Anne-Marie L.,Leigh, David A.,Lusby, Paul J.,Slawin, Alexandra M. Z.,Walker, D. Barney
, p. 12612 - 12619 (2007/10/03)
We report the synthesis of a [2]catenate using a square planar palladium(II) template, together with two isomers of the interlocked structure: a single tetradentate macrocycle that adopts a "figure of eight" conformation to encapsulate the metal and a com
