86636-00-2

Basic information

• Product Name: Phenol, 4-methoxy-3-(1-methylethoxy)-
• CAS NO: 86636-00-2
• Molecular Formula: C10H14O3
• Molecular Weight: 182.219
• Mol File: 86636-00-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Phenol, 4-methoxy-3-(1-methylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-methoxy-3-(1-methylethoxy)-(86636-00-2)
• EPA Substance Registry System: Phenol, 4-methoxy-3-(1-methylethoxy)-(86636-00-2)

Safety Data

• Hazardous Substances Data: 86636-00-2(Hazardous Substances Data)

Upstream product

• 86635-95-2 1,4-dimethoxy-2-isopropyloxybenzene 
• 621-59-0 isovanillin 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 13330-65-9 2,4-dimethoxyphenol 
• 34123-66-5 O-isopropylisovanillin 

Downstream Products

• 149355-75-9 14-(3,4-dimethoxyphenyl)-3-hydroxy-2,10,11,12-tetramethoxy-8,9-dihydro-6H-chromeno[4’,3’:4,5]pyrrolo[2,1-a]isoquinolin-6-one 
• 97614-64-7 14-(4-hydroxy-3-methoxyphenyl)-3-hydroxy-2,10,11,12-tetramethoxy-8,9-dihydro-6H-chromeno[4’,3’:4,5]pyrrolo[2,1-a]isoquinolin-6-one 
• 271243-11-9 8,9-dihydro-3,11-diisopropoxy-14-(3-isopropoxy-4-methoxyphenyl)-2,12-dimethoxy-6H-[1]benzopyrano[4′,3′:4,5]pyrrolo[2,1-α]isoquinolin-6-one 
• 149379-26-0 3,11-dihydroxy-14-(3-hydroxy-4-methoxyphenyl)-2,12-dimethoxy-6H-[1]benzopyrano-[4′,3′:4,5]pyrrolo[2,1-a]isoquinolin-6-one 
• 97614-65-8 lamellarin D 
• 149378-57-4 3,11-dihydroxy-14-(3-hydroxy-4-methoxyphenyl)-2,12-dimethoxy-8,9-dihydro-6H-[1]benzopyrano-[4′,3′:4,5]pyrrolo-[2,1-a]isoquinolin-6-one 
• 875654-44-7 3,4-dihydro-7-isopropoxy-1-(3-isopropoxy-4-methoxyphenyl)-3-[2-(3-isopropoxy-4-methoxyphenyl)ethyl]-8-methoxy-4-oxo-[1]benzopyrano[3,4-b]pyrrole-2-carboxylic acid 
• 875654-42-5 methyl 3,4-dihydro-7-isopropoxy-1-(3-isopropoxy-4-methoxyphenyl)-3-[2-(3-isopropoxy-4-methoxyphenyl)ethyl]-8-methoxy-4-oxo-[1]benzopyrano[3,4-b]pyrrole-2-carboxylate 
• 875654-41-4 methyl 3,4-dihydro-7-isopropoxy-1-(4-isopropoxy-3-methoxyphenyl)-3-[2-(3-isopropoxy-4-methoxyphenyl)ethyl]-8-methoxy-4-oxo-[1]benzopyrano[3,4-b]pyrrole-2-carboxylate 
• 875654-43-6 3,4-dihydro-7-isopropoxy-1-(4-isopropoxy-3-methoxyphenyl)-3-[2-(3-isopropoxy-4-methoxyphenyl)ethyl]-8-methoxy-4-oxo-[1]benzopyrano[3,4-b]pyrrole-2-carboxylic acid 
• 660396-69-0 5,6-dihydro-3,11-diisopropoxy-14-(4-isopropoxy-3-methoxyphenyl)-2,12-dimethoxy-6H-[1]benzopyrano[4',3':4,5]pyrrolo[2,1-a]isoquinolin-6-one 
• 660396-67-8 3,11-diisopropoxy-14-(4-isopropoxy-3-methoxyphenyl)-2,12-dimethoxy-6H-chromeno[4′,3′:4,5]pyrrolo[2,1-a]-isoquinolin-6-one 
• 875654-45-8 3,11-diisopropoxy-14-(3-isopropoxy-4-methoxyphenyl)-2,12-dimethoxy-6H-[1]benzopyrano[4′,3′:4,5]pyrrolo[2,1-a]-isoquinolin-6-one 
• 875654-30-1 7-isopropoxy-1-(4-isopropoxy-3-methoxyphenyl)-3-[2-(3-isopropoxy-4-methoxyphenyl)ethyl]-8-methoxy-4-oxo-[1]benzopyrano[3,4-b]pyrrol-4(3H)-one 

Relevant articles and documents

Concise Synthesis of Lamellarin Alkaloids by C-H/N-H Activation: Evaluation of Metal Catalysts in Oxidative Alkyne Annulation

The performance of various transition-metal catalysts was explored in the step-economical synthesis of naturally occurring lamellarin alkaloids by C-H/N-H activation. The oxidative alkyne annulation proceeded efficiently by using sustainable ruthenium(II) catalysis, which set the stage for a concise synthesis of lamellarin D, lamellarin H and derivatives thereof.

Total synthesis of lamellarins D, L, and N

Total synthesis of cytotoxic marine alkaloids, lamellarins D, L, and N, has been achieved by using Hinsberg-type pyrrole synthesis and palladium-catalyzed Suzuki-Miyaura coupling of the 3,4-dihydroxypyrrole bistriflate 6 as the key reactions. The total yields of lamellarins D, L, and N from the common intermediate 6 are 54, 58, and 50%, respectively.

Selective cleavage of isopropyl aryl ethers by aluminum trichloride

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