866416-69-5Relevant academic research and scientific papers
Synthetic studies on thiostrepton family of peptide antibiotics: Synthesis of the dihydroquinoline portion of thiostrepton, the siomycins, and the thiopeptins
Mori, Tomonori,Satouchi, Yukiko,Tohmiya, Hiraku,Higashibayashi, Shuhei,Hashimoto, Kimiko,Nakata, Masaya
, p. 6417 - 6422 (2005)
Synthesis of the dihydroquinoline portion of thiostrepton, the siomycins, and the thiopeptins, members of the thiostrepton family of peptide antibiotics, has been achieved featuring the one-pot olefination via the Matsumura- Boekelheide rearrangement "using trifluoromethanesulfonic anhydride and triethylamine" and the stereoselective addition reaction controlled by the stereocenter of the peri-position.
