866430-81-1

Basic information

• Product Name: [(1R,2S,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester
• Synonyms: [(1R,2S,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester
• CAS NO: 866430-81-1
• Molecular Weight: 368.589
• Mol File: 866430-81-1.mol

Chemical Properties

• CAS DataBase Reference: [(1R,2S,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(1R,2S,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester(866430-81-1)
• EPA Substance Registry System: [(1R,2S,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester(866430-81-1)

Safety Data

• Hazardous Substances Data: 866430-81-1(Hazardous Substances Data)

Upstream product

• 162662-48-8 (1S,4R,4aS,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-4,4a,8,8a-tetrahydro-1H-1,4-methano-naphthalen-5-one 
• 866430-79-7 [(1R,5R,6R)-6-But-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohex-3-enyl]-acetic acid ethyl ester 

Downstream Products

• 866430-88-8 (1R,4S,4aR,8R,12aR)-1-(tert-Butyl-dimethyl-silanyloxy)-4-(tert-butyl-diphenyl-silanyloxy)-8-methyl-1,4,4a,5,8,9,10,11,12,12a-decahydro-7-oxa-benzocyclodecen-6-one 
• 866430-86-6 [6-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid 1-methyl-allyl ester 
• 866430-87-7 (Z)-(1R,4S,4aR,8R,12aR)-1-(tert-Butyl-dimethyl-silanyloxy)-4-(tert-butyl-diphenyl-silanyloxy)-8-methyl-1,4,4a,5,8,11,12,12a-octahydro-7-oxa-benzocyclodecen-6-one 
• 866430-89-9 (1R,4S,4aR,8R,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-8-methyl-1,4,4a,5,8,9,10,11,12,12a-decahydro-7-oxa-benzocyclodecen-6-one 
• 883746-93-8 (4S,4aR,8R,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-8-methyl-4a,5,8,9,10,11,12,12a-octahydro-4H-7-oxa-benzocyclodecene-1,6-dione 
• 866430-85-5 [6-but-3-enyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid ethyl ester 

Relevant articles and documents

Enantioselective synthesis of epi-(+)-Sch 642305: Observation of an interesting diastereoselection during RCM

In an approach towards the enantioselective total synthesis of the novel bioactive natural product Sch 642305, an unusual diastereoselection during the key RCM reaction, resulted in the synthesis of the 11-epi-isomer of Sch 642305.