866454-58-2

Upstream product

• 866454-55-9 3-methoxy-2-(4-methoxybenzyloxy)-5-methylhex-5-en-1-ol 
• 1402588-67-3 C₁₁H₁₄O₄ 
• 152386-84-0 (2R,3R)-2-O-(4-methoxybenzyl)-1,2,3,4-butanetetrol 
• 866454-54-8 3-methoxy-2-(4-methoxybenzyloxy)-5-methylhex-5-en-1-ol 

Downstream Products

• 1402588-84-4 C₅₁H₈₃NO₁₂Si₂ 
• 1402589-26-7 C₅₁H₈₃NO₁₂Si₂ 
• 1402588-85-5 C₅₈H₈₇NO₁₃Si₂ 
• 1402588-86-6 C₅₀H₇₉NO₁₂Si₂ 
• 866454-61-7 3-methoxy-2-(4-methoxybenzyloxy)-5-methylhex-5-enoic acid methyl ester 
• 866454-46-8 3-methoxy-2-(4-methoxybenzyloxy)-5-methylhex-5-enoic acid 

Relevant academic research and scientific papers

Studies toward the unique pederin family member psymberin: Full structure elucidation, two alternative total syntheses, and analogs

Two synthetic approaches to psymberin have been accomplished. A highly convergent first generation synthesis led to the complete stereochemical assignment and demonstrated that psymberin and irciniastatin A are identical compounds. This synthesis featured

Stereochemical assignment of the C1-C6 fragment of psymberin by synthesis and natural product degradation

(Chemical Equation Presented) Psymberin is a sponge-derived natural product that shows striking selectivity as a cytotoxic agent. Conformational mobility has precluded stereochemical assignment for the acyl fragment of this molecule (psymberic acid) by NM