866454-72-0Relevant academic research and scientific papers
Rhodium-catalyzed asymmetric nitroallylation of arylmetallics with cyclic nitroallyl acetates and applications in organic synthesis
Dong, Lin,Xu, Yan-Jun,Yuan, Wei-Cheng,Cui, Xin,Cun, Lin-Feng,Gong, Liu-Zhu
, p. 4093 - 4105 (2007/10/03)
Highly enantioselective rhodium-catalyzed nitroallylations of arylboronic acids and arylzinc chlorides with cyclic nitroallyl acetates are described. Catalyst screening indicated that the rhodium complex of [Rh(OH)(CODJ] 2 and optically pure bi
Asymmetric nitroallylation of arylboronic acids with nitroallyl acetates catalyzed by chiral rhodium complexes and its application in a concise total synthesis of optically pure (+)-γ-lycorane
Dong, Lin,Xu, Yan-Jun,Cun, Lin-Feng,Cui, Xin,Mi, Ai-Qiao,Jiang, Yao-Zhong,Gong, Liu-Zhu
, p. 4285 - 4288 (2007/10/03)
(Chemical Equation Presented) A new rhodium-catalyzed highly enantioselective nitroallylation of 2-nitrocyclohex-2-enol esters with arylboronic acids is described. A rhodium complex of [RhOH(COD)]2 and optically pure BINAP is the optimal cataly
